De Luca, M., Gupta, H., Neufeld, D., Gerin, M., Teyssier, D., Drouin, B. J., et al. (2012). Herschel/HIFI discovery of HCL+ in the interstellar medium. Astrophys. J. Lett., 751(2), L37.
Abstract: The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models.
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Dedes, C., Röllig, M., Mookerjea, B., Okada, Y., Ossenkopf, V., Bruderer, S., et al. (2010). The origin of the [C II] emission in the S140 photon-dominated regions. New insights from HIFI. Astron. Astrophys., 521, L24.
Abstract: Using Herschel's HIFI instrument, we observe C ii along a cut through S140, as well as high-J transitions of CO and HCO+ at two positions on the cut, corresponding to the externally irradiated ionization front and the embedded massive star-forming core IRS1. The HIFI data were combined with available ground-based observations and modeled using the KOSMA-Ï„ model for photon-dominated regions (PDRs). We derive the physical conditions in S140 and in particular the origin of C ii emission around IRS1. We identify three distinct regions of C ii emission from the cut, one close to the embedded source IRS1, one associated with the ionization front, and one further into the cloud. The line emission can be understood in terms of a clumpy model of PDRs. At the position of IRS1, we identify at least two distinct components contributing to the [C ii] emission, one of them a small, hot component, which can possibly be identified with the irradiated outflow walls. This is consistent with the C ii peak at IRS1 coinciding with shocked H2 emission at the edges of the outflow cavity. We note that previously available observations of IRS1 can be reproduced well by a single-component KOSMA-Ï„ model. Thus, it is HIFI's unprecedented spatial and spectral resolution, as well as its sensitivity that has allowed us to uncover an additional hot gas component in the S140 region.
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Mookerjea, B., Giesen, T., Stutzki, J., Cernicharo, J., Goicoechea, J. R., De Luca, M., et al. (2010). Excitation and abundance of C3 in star forming cores. Herschel/HIFI observations of the sight-lines to W31C and W49N. Astron. Astrophys., 521, L13.
Abstract: We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy ν2 bending mode at frequencies between 1654–1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (Trot) of ~50-70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived Trot, we get column densities N(C3) ~ 7–9 × 1014 cm-2 and abundance x(C3) ~ 10-8 with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3) = 10-8, Tkin = 30–50 K, N(C3) = 1.5 × 1015 cm-2 fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis.
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Hartogh, P., Jarchow, C., Lellouch, E., de Val-Borro, M., Rengel, M., Moreno, R., et al. (2010). Herschel/HIFI observations of Mars: First detection of O2 at submillimetre wavelengths and upper limits on HCl and H2O2. Astron. Astrophys., 521, L49.
Abstract: We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements.
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