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Parrott, Edward P. J.; Zeitler, J. Axel; Fris<cc><152>c<cc><152>ic<cc><81>, Tomislav; Pepper, Michael; Jones, William; Day, Graeme M.; Gladden, Lynn F. |
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Title |
Testing the sensitivity of terahertz spectroscopy to changes in molecular and supramolecular structure: a study of structurally similar cocrystals |
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Journal Article |
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Year |
2009 |
Publication |
Crystal Growth & Design |
Abbreviated Journal |
Crystal Growth & Design |
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9 |
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3 |
Pages |
1452-1460 |
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Keywords |
supramolecular recognition, infrared, terahertz, IR, THz, TDS |
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Abstract |
Terahertz time-domain-spectroscopy (THz-TDS) has emerged as a versatile spectroscopic technique, and an alternative to powder X-ray diffraction in the characterization of molecular crystals. We tested the ability of terahertz spectroscopy to distinguish between chiral and racemic hydrogen-bonded cocrystals that are similar in molecular and supramolecular structure. Terahertz spectroscopy readily distinguished between the isostructural cocrystals of theophylline with chiral and racemic forms of malic acid which are almost identical in molecular structure and supramolecular architecture. Similarly, the cocrystals of theophylline with chiral and racemic forms of tartaric acid, which are similar at the molecular level but dissimilar in crystal packing, were distinguished unequivocally. The investigation of the same cocrystals using X-ray powder diffraction and Raman spectroscopy suggested that THz-TDS is comparable in sensitivity to diffraction methods and more sensitive than Raman spectroscopy to changes in cocrystal architecture. The differences in spectra acquired by THz-TDS could be further enhanced by cooling the samples to 109 K. |
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1528-7483 |
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567 |
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Lieberzeit, P.; Afzal, A.; Rehman, A.; Dickert, F. |
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Title |
Nanoparticles for detecting pollutants and degradation processes with mass-sensitive sensors |
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Journal Article |
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2007 |
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Sensors and Actuators B: Chemical |
Abbreviated Journal |
Sensors and Actuators B: Chemical |
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127 |
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1 |
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132-136 |
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molecular imprinted polymer, MIP, recognition, quartz crystal microbalance, QCM, mass-sensitive sensor, detector |
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Compared with thin films, nanoparticle layers as coatings for QCM offer substantially increased interaction areas and sensitivities with favourable response times. Molybdenum disulphide (MoS2), e.g. has turned out to be a highly suitable material for interacting with thiols. The resulting materials are sufficiently soft according to Pearson to bind sulphur containing compounds reversibly. Depositing MoS2 nanoparticle submonolayers (particle size 200–300 nm) leads to an increase in sensor response by a factor of ten compared to a pure gold layer. Additionally, the nanoparticle layers show fully reversible sensor signals. Particle synthesis can also be combined with the molecular imprinting approach: by a precipitation technique, it is possible to generate molecularly imprinted TiO2 particles for engine oil degradation measurements. Compared with deposited thin layers, particles incorporate oxidised compounds from lubricants by a factor of two better. |
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0925-4005 |
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568 |
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Kampfrath, Tobias; Perfetti, Luca; von Volkmann, Konrad; Aguirre, Carla M.; Desjardins, Patrick; Martel, Richard; Frischkorn, Christian; Wolf, Martin |
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Optical response of single-wall carbon nanotube sheets in the far-infrared spectral range from 1 THz to 40 THz |
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Journal Article |
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2007 |
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Physica Status Solidi (B) |
Abbreviated Journal |
Phys. Stat. Sol. (B) |
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244 |
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11 |
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3950-3954 |
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single wall, carbon nanotube, SWNT, SWCNT, CNT, detector, sensor, TDS |
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The optical properties of single-wall carbon nanotube sheets in the far-infrared have been investigated with THz time-domain spectroscopy. Over a wide frequency range from 1 THz to 40 THz, the complex dielectric function of the nanotube sample has been derived. Our data can be excellently reproduced by a Drude-Lorentz model function. The extracted fit parameters such as Lorentz resonance frequency and plasma frequency are consistent with values obtained by scanning tunneling techniques. We discuss the origin of both the Lorentz and Drude contribution in terms of direct and indirect optical transitions. |
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0370-1972 |
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569 |
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Kawano, Yukio; Ishibashi, Koji |
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An on-chip near-field terahertz probe and detector |
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Journal Article |
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2008 |
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Nature Photonics |
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Nature Photon |
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2 |
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10 |
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618-621 |
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single molecule, terahertz, THz, near-field, microscopy, imaging, 2DEG, GaAs/AlGaAs, detector, applications |
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The advantageous properties of terahertz waves, such as their transmission through objects opaque to visible light, are attracting attention for imaging applications. A promising approach for achieving high spatial resolution is the use of near-field imaging. Although this method has been well established in the visible and microwave regions, it is challenging to perform in the terahertz region. In the terahertz techniques investigated to date, detectors have been located remotely from the probe, which degrades sensitivity, and the influence of far-field waves is unavoidable. Here we present a new integrated detection device for terahertz near-field imaging in which all the necessary detection components — an aperture, a probe and a terahertz detector — are integrated on one semiconductor chip, which is cryogenically cooled. This scheme allows highly sensitive, high-resolution detection of the evanescent field alone and promises new capabilities for high-resolution terahertz imaging. |
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1749-4885 |
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570 |
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Siddiqi, I.; Prober, D. E. |
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Nb–Au bilayer hot-electron bolometers for low-noise THz heterodyne detection |
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Journal Article |
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Year |
2004 |
Publication |
Applied Physics Letters |
Abbreviated Journal |
Appl. Phys. Lett. |
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84 |
Issue |
8 |
Pages |
1404 |
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HEB, mixers, dynamic range, saturation, LO power, local oscillator power, Nb |
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The sensitivity of present Nb diffusion-cooled hot-electron bolometer (HEB) mixers is not quantum limited, and can be improved by reducing the superconducting transition temperature TC. Lowering TC reduces thermal fluctuations, resulting in a decrease of the mixer noise temperature TM. However, lower TC mixers have reduced dynamic range and saturate more easily due to background noise. We present 30 GHz microwave measurements on a bilayer HEB system, Nb–Au, in which TC can be tuned with Au layer thickness to obtain the maximum sensitivity for a given noise background. These measurements are intended as a guide for the optimization of THz mixers. Using a Nb–Au mixer with TC = 1.6 K, we obtain TM = 50 K with 2 nW of local oscillator (LO) power. Good mixer performance is observed over a wide range of LO power and bias voltage and such a device should not exhibit saturation in a THz receiver. |
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0003-6951 |
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571 |
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