Abstract: Compared with thin films, nanoparticle layers as coatings for QCM offer substantially increased interaction areas and sensitivities with favourable response times. Molybdenum disulphide (MoS2), e.g. has turned out to be a highly suitable material for interacting with thiols. The resulting materials are sufficiently soft according to Pearson to bind sulphur containing compounds reversibly. Depositing MoS2 nanoparticle submonolayers (particle size 200–300 nm) leads to an increase in sensor response by a factor of ten compared to a pure gold layer. Additionally, the nanoparticle layers show fully reversible sensor signals. Particle synthesis can also be combined with the molecular imprinting approach: by a precipitation technique, it is possible to generate molecularly imprinted TiO2 particles for engine oil degradation measurements. Compared with deposited thin layers, particles incorporate oxidised compounds from lubricants by a factor of two better.

Abstract: The advantageous properties of terahertz waves, such as their transmission through objects opaque to visible light, are attracting attention for imaging applications. A promising approach for achieving high spatial resolution is the use of near-field imaging. Although this method has been well established in the visible and microwave regions, it is challenging to perform in the terahertz region. In the terahertz techniques investigated to date, detectors have been located remotely from the probe, which degrades sensitivity, and the influence of far-field waves is unavoidable. Here we present a new integrated detection device for terahertz near-field imaging in which all the necessary detection components — an aperture, a probe and a terahertz detector — are integrated on one semiconductor chip, which is cryogenically cooled. This scheme allows highly sensitive, high-resolution detection of the evanescent field alone and promises new capabilities for high-resolution terahertz imaging.