Mookerjea, B., Giesen, T., Stutzki, J., Cernicharo, J., Goicoechea, J. R., De Luca, M., et al. (2010). Excitation and abundance of C3 in star forming cores. Herschel/HIFI observations of the sight-lines to W31C and W49N. Astron. Astrophys., 521, L13.
Abstract: We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy ν2 bending mode at frequencies between 1654–1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (Trot) of ~50-70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived Trot, we get column densities N(C3) ~ 7–9 × 1014 cm-2 and abundance x(C3) ~ 10-8 with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3) = 10-8, Tkin = 30–50 K, N(C3) = 1.5 × 1015 cm-2 fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis.
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Melnick, G. J., Tolls, V., Neufeld, D. A., Bergin, E. A., Phillips, T. G., Wang, S., et al. (2010). Herschel observations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL. Astron. Astrophys., 521, L27.
Abstract: We report the detection of more than 48 velocity-resolved ground rotational state transitions of H216O, H218O, and H217O – most for the first time – in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H218O line fluxes, which are less affected by line opacity than their H216O counterparts, and an escape probability method, the column densities of H218O associated with each emission component are derived. We infer total water abundances of 7.4 × 10-5, 1.0 × 10-5, and 1.6 × 10-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources.
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Maret, S., Bacmann, A., Bottinelli, S., Parise, B., Caux, E., Faure, A., et al. (2010). Nitrogen hydrides in the cold envelope of IRAS 16293-2422. Astron. Astrophys., 521, L52.
Abstract: Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes.
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Loenen, A. F., van der Werf, P. P., Güsten, R., Meijerink, R., Israel, F. P., Requena-Torres, M. A., et al. (2010). Excitation of the molecular gas in the nuclear region of M 82. Astron. Astrophys., 521, L2.
Abstract: We present high-resolution HIFI spectroscopy of the nucleus of the archetypical starburst galaxy M 82. Six 12CO lines, 2 13CO lines and 4 fine-structure lines have been detected. Besides showing the effects of the overall velocity structure of the nuclear region, the line profiles also indicate the presence of multiple components with different optical depths, temperatures, and densities in the observing beam. The data have been interpreted using a grid of PDR models. It is found that the majority of the molecular gas is in low density (n = 103.5 cm-3) clouds, with column densities of NH = 1021.5 cm-2 and a relatively low UV radiation field (G0 = 102). The remaining gas is predominantly found in clouds with higher densities (n = 105 cm-3) and radiation fields (G0 = 102.75), but somewhat lower column densities (NH = 1021.2 cm-2). The highest J CO lines are dominated by a small (1% relative surface filling) component, with an even higher density (n = 106 cm-3) and UV field (G0 = 103.25). These results show the strength of multi-component modelling for interpretating the integrated properties of galaxies.
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Käufl, H. U., Rothermal, H., & Drapatz, S. (1984). Investigation of the Martian atmosphere by 10 micron heterodyne spectroscopy. A&A, 136, 319–325.
Keywords: astronomical spectroscopy, atmospheric composition, infrared astronomy, mars atmosphere, spectral line width, carbon dioxide concentration, nonequilibrium thermodynamics, optical heterodyning, planetary radiation, mars, atmosphere, spectroscopy, atmosphere, carbon dioxide, altitude, kinetics, rotation, thermal properties, temperature, emissions, intensity, models, data, spectra
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Kaeufl, H. U., Rothermel, H., & Drapatz, S. (1984). Indication for H2O in the upper atmosphere of Mars. A&A, 141, 430–432.
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Justtanont, K., Decin, L., Schöier, F. L., Maercker, M., Olofsson, H., Bujarrabal, V., et al. (2010). A HIFI preview of warm molecular gas around χ Cygni: first detection of H2O emission toward an S-type AGB star. Astron. Astrophys., 521, L6.
Abstract: Aims. A set of new, sensitive, and spectrally resolved, sub-millimeter line observations are used to probe the warm circumstellar gas around the S-type AGB star χ Cyg. The observed lines involve high rotational quantum numbers, which, combined with previously obtained lower-frequency data, make it possible to study in detail the chemical and physical properties of, essentially, the entire circumstellar envelope of χ Cyg.
Methods. The data were obtained using the HIFI instrument aboard Herschel, whose high spectral resolution provides valuable information about the line profiles. Detailed, non-LTE, radiative transfer modelling, including dust radiative transfer coupled with a dynamical model, has been performed to derive the temperature, density, and velocity structure of the circumstellar envelope.
Results. We report the first detection of circumstellar H2O rotational emission lines in an S-star. Using the high-J CO lines to derive the parameters for the circumstellar envelope, we modelled both the ortho- and para-H2O lines. Our modelling results are consistent with the velocity structure expected for a dust-driven wind. The derived total H2O abundance (relative to H2) is (1.1±0.2) × 10-5, much lower than that in O-rich stars. The derived ortho-to-para ratio of 2.1±0.6 is close to the high-temperature equilibrium limit, consistent with H2O being formed in the photosphere.
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Johnson, M. A., Betz, A. L., McLaren, R. A., Townes, C. H., & Sutton, E. C. (1976). Nonthermal 10 micron CO2 emission lines in the atmospheres of Mars and Venus. A&A, 208, 145.
Keywords: carbon dioxide, emission spectra, infrared spectra, mars atmosphere, nonthermal radiation, optical heterodyning, planetary radiation, venus atmosphere, absorption spectra, energy transfer, line spectra, molecular absorption, molecular collisions, near infrared radiation, solar flux
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Joblin, C., Pilleri, P., Montillaud, J., Fuente, A., Gerin, M., Berné, O., et al. (2010). Gas morphology and energetics at the surface of PDRs: New insights with Herschel observations of NGC 7023. Astron. Astrophys., 521, L25.
Abstract: Context. We investigate the physics and chemistry of the gas and dust in dense photon-dominated regions (PDRs), along with their dependence on the illuminating UV field.
Aims. Using Herschel/HIFI observations, we study the gas energetics in NGC 7023 in relation to the morphology of this nebula. NGC 7023 is the prototype of a PDR illuminated by a B2V star and is one of the key targets of Herschel.
Methods. Our approach consists in determining the energetics of the region by combining the information carried by the mid-IR spectrum (extinction by classical grains, emission from very small dust particles) with that of the main gas coolant lines. In this letter, we discuss more specifically the intensity and line profile of the 158 μm (1901 GHz) [C ii] line measured by HIFI and provide information on the emitting gas.
Results. We show that both the [C ii] emission and the mid-IR emission from polycyclic aromatic hydrocarbons (PAHs) arise from the regions located in the transition zone between atomic and molecular gas. Using the Meudon PDR code and a simple transfer model, we find good agreement between the calculated and observed [C ii] intensities.
Conclusions. HIFI observations of NGC 7023 provide the opportunity to constrain the energetics at the surface of PDRs. Future work will include analysis of the main coolant line [O i] and use of a new PDR model that includes PAH-related species.
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Hartogh, P., Jarchow, C., Lellouch, E., de Val-Borro, M., Rengel, M., Moreno, R., et al. (2010). Herschel/HIFI observations of Mars: First detection of O2 at submillimetre wavelengths and upper limits on HCl and H2O2. Astron. Astrophys., 521, L49.
Abstract: We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements.
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