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Lieberzeit, P. A., & Dickert, F. L. (2009). Chemosensors in environmental monitoring: challenges in ruggedness and selectivity. Anal Bioanal Chem, 393(2), 467–472.
Abstract: Environmental analysis is a potential key application for chemical sensors owing to their inherent ability to detect analytes on-line and in real time in distributed systems. Operating a chemosensor in a natural environment poses substantial challenges in terms of ruggedness, long-term stability and calibration. This article highlights current trends of achieving both the necessary selectivity and ruggedness: one way is deploying sensor arrays consisting of robust broadband sensors and extracting information via chemometrics. If using only a single sensor is desired, molecularly imprinted polymers offer a straightforward way for designing artificial recognition materials. Molecularly imprinted polymers can be utilized in real-life environments, such as water and air, aiming at detecting analytes ranging from small molecules to entire cells.
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Parrott, E. P. J., Zeitler, J. A., Fris<cc><152>c<cc><152>ic<cc><81>, T., Pepper, M., Jones, W., Day, G. M., et al. (2009). Testing the sensitivity of terahertz spectroscopy to changes in molecular and supramolecular structure: a study of structurally similar cocrystals. Crystal Growth & Design, 9(3), 1452–1460.
Abstract: Terahertz time-domain-spectroscopy (THz-TDS) has emerged as a versatile spectroscopic technique, and an alternative to powder X-ray diffraction in the characterization of molecular crystals. We tested the ability of terahertz spectroscopy to distinguish between chiral and racemic hydrogen-bonded cocrystals that are similar in molecular and supramolecular structure. Terahertz spectroscopy readily distinguished between the isostructural cocrystals of theophylline with chiral and racemic forms of malic acid which are almost identical in molecular structure and supramolecular architecture. Similarly, the cocrystals of theophylline with chiral and racemic forms of tartaric acid, which are similar at the molecular level but dissimilar in crystal packing, were distinguished unequivocally. The investigation of the same cocrystals using X-ray powder diffraction and Raman spectroscopy suggested that THz-TDS is comparable in sensitivity to diffraction methods and more sensitive than Raman spectroscopy to changes in cocrystal architecture. The differences in spectra acquired by THz-TDS could be further enhanced by cooling the samples to 109 K.
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Минаева, О. В. (2009). Быстродействующий однофотонный детектор на основе тонкой сверхпроводниковой пленки NbN. Ph.D. thesis, , .
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Ryabchun, S. A., Tretyakov, I. V., Finkel, M. I., Maslennikov, S. N., Kaurova, N. S., Seleznev, V. A., et al. (2009). NbN phonon-cooled hot-electron bolometer mixer with additional diffusion cooling. In Proc. 20th Int. Symp. Space Terahertz Technol. (pp. 151–154). Charlottesville, USA.
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Рябчун, С. А. (2009). Широкополосные высокостабильные терагерцовые смесители на горячих электронах из тонких сверхпроводниковых пленок NbN. Ph.D. thesis, , .
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