| Records |
| Author |
De Luca, M.; Gupta, H.; Neufeld, D.; Gerin, M.; Teyssier, D.; Drouin, B. J.; Pearson, J. C.; Lis, D. C.; Monje, R.; Phillips, T. G.; Goicoechea, J. R.; Godard, B.; Falgarone, E.; Coutens, A.; Bell, T. A. |
| Title |
Herschel/HIFI discovery of HCL+ in the interstellar medium |
Type |
Journal Article |
| Year |
2012 |
Publication |
Astrophys. J. Lett. |
Abbreviated Journal |
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| Volume |
751 |
Issue |
2 |
Pages  |
L37 |
| Keywords |
HEB mixer applications, HIFI, Herschel |
| Abstract |
The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models. |
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1092 |
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Maret, S.; Bacmann, A.; Bottinelli, S.; Parise, B.; Caux, E.; Faure, A.; Bergin, E. A.; Blake, G. A.; Castets, A.; Ceccarelli, C.; Cernicharo, J.; Coutens, A.; Crimier, N.; Demyk, K.; Dominik, C.; Gerin, M.; Hennebelle, P.; Henning, T.; Kahane, C.; Klotz, A.; Melnick, G.; Pagani, L.; Schilke, P.; Vastel, C.; Wakelam, V.; Walters, A.; Baudry, A.; Bell, T.; Benedettini, M.; Boogert, A.; Cabrit, S.; Caselli, P.; Codella, C.; Comito, C.; Encrenaz, P.; Falgarone, E.; Fuente, A.; Goldsmith, P. F.; Helmich, F.; Herbst, E.; Jacq, T.; Kama, M.; Langer, W.; Lefloch, B.; Lis, D.; Lord, S.; Lorenzani, A.; Neufeld, D.; Nisini, B.; Pacheco, S.; Phillips, T.; Salez, M.; Saraceno, P.; Schuster, K.; Tielens, X.; van der Tak, F.; van der Wiel, M. H. D.; Viti, S.; Wyrowski, F.; Yorke, H. |
| Title |
Nitrogen hydrides in the cold envelope of IRAS 16293-2422 |
Type |
Journal Article |
| Year |
2010 |
Publication |
Astron. Astrophys. |
Abbreviated Journal |
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| Volume |
521 |
Issue |
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Pages |
L52 |
| Keywords |
HEB mixer applications, HIFI, Herschel, ISM: abundances / ISM: general / astrochemistry |
| Abstract |
Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes. |
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1094 |
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Phillips, T. G.; Jefferts, K. B. |
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A low temperature bolometer heterodyne receiver for Millimeter wave astronomy |
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Journal Article |
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1973 |
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Rev. Sci. Instrum. |
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Rev. Sci. Instrum. |
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44 |
Issue |
8 |
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1009-1014 |
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InSb HEB mixer |
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Liquid helium cooled InSb hot electronbolometers are used in a balanced mixer configuration as detectors for an imagelessmicrowave receiver. The system is designed for mounting at the prime focus of the National Radio Astronomy Observatory (NRAO) 11 m antenna at Kitt Peak, Arizona, and is suitable for the study of rotational line spectra of interstellar gas molecules. Currently the operating frequency is in the 90–140 GHz band where the double sideband system noise temperature is 250 K. |
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Recommended by Klapwijk |
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927 |
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Gordon, N. T.; Lees, D. J.; Bowen, G.; Phillips, T. S.; Haigh, M.; Jones, C. L.; Maxey, C. D.; Hipwood, L.; Catchpole, R. A. |
| Title |
HgCdTe detectors operating above 200 K |
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Journal Article |
| Year |
2006 |
Publication |
J. Electron. Mater. |
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35 |
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6 |
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1140-1144 |
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HgCdTe detector |
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0361-5235 |
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467 |
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de Graauw, T.; Caux, E.; Guesten, R.; Helmich, F.; Pearson, J.; Phillips, T. G.; Schieder, R.; Tielens, X.; Saraceno, P.; Stutzki, J.; Wafelbakker, C. K.; Whyborn, N. D. |
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The Herschel-heterodyne instrument for the far-infrared (HIFI) |
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Conference Article |
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2005 |
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Bulletin of the American Astronomical Society |
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1219 |
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Bulletin of the American Astronomical Society |
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37 |
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ref2005AAS...207.3503D |
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420 |
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