| Records |
| Author |
Parrott, Edward P. J.; Zeitler, J. Axel; Fris<cc><152>c<cc><152>ic<cc><81>, Tomislav; Pepper, Michael; Jones, William; Day, Graeme M.; Gladden, Lynn F. |
| Title |
Testing the sensitivity of terahertz spectroscopy to changes in molecular and supramolecular structure: a study of structurally similar cocrystals |
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Journal Article |
| Year |
2009 |
Publication |
Crystal Growth & Design |
Abbreviated Journal |
Crystal Growth & Design |
| Volume |
9 |
Issue |
3 |
Pages |
1452-1460 |
Keywords  |
supramolecular recognition, infrared, terahertz, IR, THz, TDS |
| Abstract |
Terahertz time-domain-spectroscopy (THz-TDS) has emerged as a versatile spectroscopic technique, and an alternative to powder X-ray diffraction in the characterization of molecular crystals. We tested the ability of terahertz spectroscopy to distinguish between chiral and racemic hydrogen-bonded cocrystals that are similar in molecular and supramolecular structure. Terahertz spectroscopy readily distinguished between the isostructural cocrystals of theophylline with chiral and racemic forms of malic acid which are almost identical in molecular structure and supramolecular architecture. Similarly, the cocrystals of theophylline with chiral and racemic forms of tartaric acid, which are similar at the molecular level but dissimilar in crystal packing, were distinguished unequivocally. The investigation of the same cocrystals using X-ray powder diffraction and Raman spectroscopy suggested that THz-TDS is comparable in sensitivity to diffraction methods and more sensitive than Raman spectroscopy to changes in cocrystal architecture. The differences in spectra acquired by THz-TDS could be further enhanced by cooling the samples to 109 K. |
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1528-7483 |
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567 |
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Baryshev, A. M.; Wild, W.; Likhachev, S. F.; Vdovin, V. F.; Goltsman, G. N.; Kardashev, N. S. |
| Title |
Main parameters and instrumentation of Millimetron space mission |
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Abstract |
| Year |
2009 |
Publication |
Proc. 20th Int. Symp. Space Terahertz Technol. |
Abbreviated Journal |
Proc. 20th ISSTT |
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Pages |
108 |
| Keywords |
SVLBI, Millimetron space observatory |
| Abstract |
Millimetron (official RosKosmos name ”Spectrum-M”) is a part of ambitious program called Spectrum intended to cover the whole electromagnetic spectrum with world class facilities. It is an approved mission included in Russian space program with the launch date in 2017..2019 time frame. The Millimetron satellite has a deployable 12 m diameter antenna with inner solid 4..6 m dish and a rim of petals. The mirror design is largely based on Radioastron mission concept that will be launched in 2009. If the antenna is passively cooled by radiation to open space, it would operate at approx. 50 K surface temperature, due to presence of a deployable three layer radiation screen. As a goal, there is a consideration of active cooling of antenna to 4 K, but this will depend on resources available to the project. Lagrangian libration point L2 considered for Millimetron orbit. There are four groups of scientific instruments envisioned: SVLBI instruments Space-Earth VLBI. It will allow to achieve unprecedented spatial resolution. Millimetron mission will attempt to achieve a mm/submm wave SVLBI. For that purpose, a SVLBI instrument covering selected ALMA bands and a standard VLBI band is envisioned, accompanied by a maser reference oscillator, a data digitizing and memory system, and a high speed data transmission link to ground. The ALMA bands can be extended to cover water lines if detector technology allows. Type of detector – heterodyne. Photometer/polarimeter. Recent progress in direct detector cameras with low spectral resolution, allows to propose a large format (5-10 kPixel) photometer camera on board of Millimetron mission. This camera can cover 0.1 – 2 THz region (with adequate amount of pixels per each subband). Wide band moderate resolution imaging spectrometer. Wide band moderate R = 1000 imaging spectrometer type instrument similar to SPICA SAFARI is planned, taking advantage of large cooled dish. It will cover the adequate spectral range allowable by antenna and will also work below 1 THz, as no ground instrument can have a cold main dish. High resolution spectrometer. For high resolution spectroscopy a heterodyne instrument is proposed, conceptually similar to HIFI on Herschel. This instrument will cover interesting frequency spots in 0.5..4 THz frequency range (using central part of antenna for higher frequency). It is sure that advances in LO and mixer technology will allow this frequency coverage. |
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Ожегов, Р.В.; Окунев, О.В.; Гольцман, Г.Н. |
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Флуктуационная чувствительность сверхпроводящего болометрического смесителя на эффекте разогрева электронного газа |
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Journal Article |
| Year |
2009 |
Publication |
Радиотехника |
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3 |
Pages |
120-124 |
| Keywords |
смеситель на горячих электронах; флуктуационная чувствительность; тепловизор терагерцевого диапазона частот; hot-electron bolometer mixer; Imaging system; Noise equivalent temperature difference; Heterodyne receiver; Terahertz range |
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Interest in research in the terahertz range is driven by a great number of various applications, where terahertz instruments may play a leading role. To name just a few, such applications include study of the cosmic microwave background radiation and the distribution of the dark matter, medicine, navigation, fire alarm, security systems and environmental monitoring. The paper discusses the possibility of using a receiver based on the hot-electron effect in superconducting films as an imaging system. We present the results of the noise equivalent temperature difference (NETD) measurements performed with a hot-electron bolometer mixer made from a thin superconducting film. The receiver with a noise temperature of ~ 3800 K at a local oscillator frequency of 300 GHz a bandwidth of 500 MHz and an integration time of 1 s has offered an NETD of 0.5 K. We have also developed a technique that enabled us to reduce the contribution of the mixer gain fluctuations to the overall system instability. As of this writing, the above value of the NETD is the lowest value offered for this type of receiver, which indicates the possibility to use such receivers in real-time imaging systems. The technique offered in the paper for achieving the limiting value of the NETD offers an alternative to the phase-locking scheme.
Представены результаты измерения флуктуационной чувствительности (NETD – noise equivalent temperature difference) болометрического смесителя на эффекте разогрева электронного газа в тонких сверхпроводящих пленках. Получено предельное значение NETD, равное 0,5 К, при шумовой температуре приемника 3800 К, ширине полосы преобразования 500 МГц, постоянной времени 1 с и частоте гетеродина 300 ГГц. Разработана методика достижения предельной флуктуационной чувствительности, позволяющая избежать влияния нестабильности коэффициента преобразования смесителя. |
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RPLAB @ gujma @ |
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728 |
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