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Author De Luca, M.; Gupta, H.; Neufeld, D.; Gerin, M.; Teyssier, D.; Drouin, B. J.; Pearson, J. C.; Lis, D. C.; Monje, R.; Phillips, T. G.; Goicoechea, J. R.; Godard, B.; Falgarone, E.; Coutens, A.; Bell, T. A.
Title Herschel/HIFI discovery of HCL+ in the interstellar medium Type Journal Article
Year 2012 Publication (down) Astrophys. J. Lett. Abbreviated Journal
Volume 751 Issue 2 Pages L37
Keywords HEB mixer applications, HIFI, Herschel
Abstract The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number Serial 1092
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Author Bruderer, S.; Benz, A. O.; van Dishoeck, E. F.; Melchior, M.; Doty, S. D.; van der Tak, F.; Stäuber, P.; Wampfler, S. F.; Dedes, C.; Yıldız, U. A.; Pagani, L.; Giannini, T.; de Graauw, Th.; Whyborn, N.; Teyssier, D.; Jellema, W.; Shipman, R.; Schieder, R.; Honingh, N.; Caux, E.; Bächtold, W.; Csillaghy, A.; Monstein, C.; Bachiller, R.; Baudry, A.; Benedettini, M.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bontemps, S.; Braine, J.; Caselli, P.; Cernicharo, J.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dominik, C.; Encrenaz, P.; Fich, M.; Fuente, A.; Goicoechea, J. R.; Helmich, F.; Herczeg, G. J.; Herpin, F.; Hogerheijde, M. R.; Jacq, T.; Johnstone, D.; Jørgensen, J. K.; Kristensen, L. E.; Larsson, B.; Lis, D.; Liseau, R.; Marseille, M.; McCoey, C.; Melnick, G.; Neufeld, D.; Nisini, B.; Olberg, M.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-García, J.; Saraceno, P.; Shipman, R.; Tafalla, M.; van Kempen, T. A.; Visser, R.; Wyrowski, F.
Title Herschel/HIFI detections of hydrides towards AFGL 2591. Envelope emission versus tenuous cloud absorption Type Journal Article
Year 2010 Publication (down) Astron. Astrophys. Abbreviated Journal
Volume 521 Issue Pages L44 (1 to 7)
Keywords HEB mixer applications, HIFI, Herschel
Abstract The Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory allows the first observations of light diatomic molecules at high spectral resolution and in multiple transitions. Here, we report deep integrations using HIFI in different lines of hydrides towards the high-mass star forming region AFGL 2591. Detected are CH, CH+, NH, OH+, H2O+, while NH+ and SH+ have not been detected. All molecules except for CH and CH+ are seen in absorption with low excitation temperatures and at velocities different from the systemic velocity of the protostellar envelope. Surprisingly, the CH(JF,P = 3/22,- – 1/21,+ ) and CH+(J = 1–0, J = 2–1) lines are detected in emission at the systemic velocity. We can assign the absorption features to a foreground cloud and an outflow lobe, while the CH and CH+ emission stems from the envelope. The observed abundance and excitation of CH and CH+ can be explained in the scenario of FUV irradiated outflow walls, where a cavity etched out by the outflow allows protostellar FUV photons to irradiate and heat the envelope at larger distances driving the chemical reactions that produce these molecules.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number Serial 1083
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Author Benz, A. O.; Bruderer, S.; van Dishoeck, E. F.; Stäuber, P.; Wampfler, S. F.; Melchior, M.; Dedes, C.; Wyrowski, F.; Doty, S. D.; van der Tak, F.; Bächtold, W.; Csillaghy, A.; Megej, A.; Monstein, C.; Soldati, M.; Bachiller, R.; Baudry, A.; Benedettini, M.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bontemps, S.; Braine, J.; Caselli, P.; Cernicharo, J.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dieleman, P.; Dominik, C.; Encrenaz, P.; Fich, M.; Fuente, A.; Giannini, T.; Goicoechea, J. R.; de Graauw, Th.; Helmich, F.; Herczeg, G. J.; Herpin, F.; Hogerheijde, M. R.; Jacq, T.; Jellema, W.; Johnstone, D.; Jørgensen, J. K.; Kristensen, L. E.; Larsson, B.; Lis, D.; Liseau, R.; Marseille, M.; McCoey, C.; Melnick, G.; Neufeld, D.; Nisini, B.; Olberg, M.; Ossenkopf, V.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-García, J.; Saraceno, P.; Schieder, R.; Shipman, R.; Stutzki, J.; Tafalla, M.; Tielens, A. G. G. M.; van Kempen, T. A.; Visser, R.; Yıldız, U. A.
Title Hydrides in young stellar objects: Radiation tracers in a protostar-disk-outflow system Type Journal Article
Year 2010 Publication (down) Astron. Astrophys. Abbreviated Journal
Volume 521 Issue Pages L35 (1 to 5)
Keywords HEB mixer applications, HIFI, Herschel
Abstract Context. Hydrides of the most abundant heavier elements are fundamental molecules in cosmic chemistry. Some of them trace gas irradiated by UV or X-rays.

Aims. We explore the abundances of major hydrides in W3 IRS5, a prototypical region of high-mass star formation.

Methods. W3 IRS5 was observed by HIFI on the Herschel Space Observatory with deep integration (2500 s) in 8 spectral regions.

Results. The target lines including CH, NH, H3O+, and the new molecules SH+, H2O+, and OH+ are detected. The H2O+ and OH+ J = 1–0 lines are found mostly in absorption, but also appear to exhibit weak emission (P-Cyg-like). Emission requires high density, thus originates most likely near the protostar. This is corroborated by the absence of line shifts relative to the young stellar object (YSO). In addition, H2O+ and OH+ also contain strong absorption components at a velocity shifted relative to W3 IRS5, which are attributed to foreground clouds.

Conclusions. The molecular column densities derived from observations correlate well with the predictions of a model that assumes the main emission region is in outflow walls, heated and irradiated by protostellar UV radiation.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number Serial 1082
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Author Chavarr'ıa, L.; Herpin, F.; Jacq, T.; Braine, J.; Bontemps, S.; Baudry, A.; Marseille, M.; van der Tak, F.; Pietropaoli, B.; Wyrowski, F.; Shipman, R.; Frieswijk, W.; van Dishoeck, E. F.; Cernicharo, J.; Bachiller, R.; Benedettini, M.; Benz, A. O.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bruderer, S.; Caselli, P.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dominik, C.; Doty, S. D.; Encrenaz, P.; Fich, M.; Fuente, A.; Giannini, T.; Goicoechea, J. R.; de Graauw, T.; Hartogh, P.; Helmich, F.; Herczeg, G. J.; Hogerheijde, M. R.; Johnstone, D.; Jørgensen, J. K.; Kristensen, L. E.; Larsson, B.; Lis, D.; Liseau, R.; McCoey, C.; Melnick, G.; Nisini, B.; Olberg, M.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-Garc'ıa, J.; Saraceno, P.; Stutzki, J.; Szczerba, R.; Tafalla, M.; Tielens, A.; van Kempen, T. A.; Visser, R.; Wampfler, S. F.; Willem, J.; Yıldız, U. A.
Title Water in massive star-forming regions: HIFI observations of W3 IRS5 Type Journal Article
Year 2010 Publication (down) Astron. Astrophys. Abbreviated Journal
Volume 521 Issue Pages L37 (1 to 5)
Keywords HEB mixer applications, HIFI, Herschel, stars: formation, stars: massive, ISM: molecules, ISM: abundances, dust, extinction, radio lines: ISM
Abstract We present Herschel observations of the water molecule in the massive star-forming region W3 IRS5. The o-H217O 110-101, p-H218O 111-000, p-H2O 202-111, p-H2O 111-000, o-H2O 221-212, and o-H2O 212-101 lines, covering a frequency range from 552 up to 1669 GHz, have been detected at high spectral resolution with HIFI. The water lines in W3 IRS5 show well-defined high-velocity wings that indicate a clear contribution by outflows. Moreover, the systematically blue-shifted absorption in the H2O lines suggests expansion, presumably driven by the outflow. No infall signatures are detected. The p-H2O 111-000 and o-H2O 212-101 lines show absorption from the cold material (T ~ 10 K) in which the high-mass protostellar envelope is embedded. One-dimensional radiative transfer models are used to estimate water abundances and to further study the kinematics of the region. We show that the emission in the rare isotopologues comes directly from the inner parts of the envelope (T â‰<b3> 100 K) where water ices in the dust mantles evaporate and the gas-phase abundance increases. The resulting jump in the water abundance (with a constant inner abundance of 10-4) is needed to reproduce the o-H217O 110-101 and p-H218O 111-000 spectra in our models. We estimate water abundances of 10-8 to 10-9 in the outer parts of the envelope (T â‰<b2> 100 K). The possibility of two protostellar objects contributing to the emission is discussed.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number Chav13HEBapplHIFIb Serial 1086
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Author Dedes, C.; Röllig, M.; Mookerjea, B.; Okada, Y.; Ossenkopf, V.; Bruderer, S.; Benz, A. O.; Melchior, M.; Kramer, C.; Gerin, M.; Güsten, R.; Akyilmaz, M.; Berne, O.; Boulanger, F.; De Lange, G.; Dubbeldam, L.; France, K.; Fuente, A.; Goicoechea, J. R.; Harris, A.; Huisman, R.; Jellema, W.; Joblin, C.; Klein, T.; Le Petit, F.; Lord, S.; Martin, P.; Martin-Pintado, J.; Neufeld, D. A.; Philipp, S.; Phillips, T.; Pilleri, P.; Rizzo, J. R.; Salez, M.; Schieder, R.; Simon, R.; Siebertz, O.; Stutzki, J.; van der Tak, F.; Teyssier, D.; Yorke, H.
Title The origin of the [C II] emission in the S140 photon-dominated regions. New insights from HIFI Type Journal Article
Year 2010 Publication (down) Astron. Astrophys. Abbreviated Journal
Volume 521 Issue Pages L24
Keywords HEB mixer applications, HIFI, Herschel, ISM: structure / ISM: kinematics and dynamics / ISM: molecules / photon-dominated region (PDR) / submillimeter: general
Abstract Using Herschel's HIFI instrument, we observe C ii along a cut through S140, as well as high-J transitions of CO and HCO+ at two positions on the cut, corresponding to the externally irradiated ionization front and the embedded massive star-forming core IRS1. The HIFI data were combined with available ground-based observations and modeled using the KOSMA-Ï„ model for photon-dominated regions (PDRs). We derive the physical conditions in S140 and in particular the origin of C ii emission around IRS1. We identify three distinct regions of C ii emission from the cut, one close to the embedded source IRS1, one associated with the ionization front, and one further into the cloud. The line emission can be understood in terms of a clumpy model of PDRs. At the position of IRS1, we identify at least two distinct components contributing to the [C ii] emission, one of them a small, hot component, which can possibly be identified with the irradiated outflow walls. This is consistent with the C ii peak at IRS1 coinciding with shocked H2 emission at the edges of the outflow cavity. We note that previously available observations of IRS1 can be reproduced well by a single-component KOSMA-Ï„ model. Thus, it is HIFI's unprecedented spatial and spectral resolution, as well as its sensitivity that has allowed us to uncover an additional hot gas component in the S140 region.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Medium
Area Expedition Conference
Notes Approved no
Call Number Serial 1091
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