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Author Wampfler, S. F.; Herczeg, G. J.; Bruderer, S.; Benz, A. O.; van Dishoeck, E. F.; Kristensen, L. E.; Visser, R.; Doty, S. D.; Melchior, M.; van Kempen, T. A.; Yıldız, U. A.; Dedes, C.; Goicoechea, J. R.; Baudry, A.; Melnick, G.; Bachiller, R.; Benedettini, M.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bontemps, S.; Braine, J.; Caselli, P.; Cernicharo, J.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dominik, C.; Encrenaz, P.; Fich, M.; Fuente, A.; Giannini, T.; de Graauw, Th.; Helmich, F.; Herpin, F.; Hogerheijde, M. R.; Jacq, T.; Johnstone, D.; Jørgensen, J. K.; Larsson, B.; Lis, D.; Liseau, R.; Marseille, M.; Mc Coey, C.; Neufeld, D.; Nisini, B.; Olberg, M.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-García, J.; Saraceno, P.; Shipman, R.; Tafalla, M.; van der Tak, F. F. S.; Wyrowski, F.; Roelfsema, P.; Jellema, W.; Dieleman, P.; Caux, E.; Stutzki, J. doi  openurl
  Title Herschel observations of the hydroxyl radical (OH) in young stellar objects Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L36  
  Keywords HEB mixer applications, HIFI, Herschel, astrochemistry / stars: formation / ISM: molecules / ISM: jets and outflows / ISM: individual objects: HH 46  
  Abstract Aims. “Water In Star-forming regions with Herschel” (WISH) is a Herschel key program investigating the water chemistry in young stellar objects (YSOs) during protostellar evolution. Hydroxyl (OH) is one of the reactants in the chemical network most closely linked to the formation and destruction of H2O. High-temperature (T 250 K) chemistry connects OH and H2O through the OH + H2 H2O + H reactions. Formation of H2O from OH is efficient in the high-temperature regime found in shocks and the innermost part of protostellar envelopes. Moreover, in the presence of UV photons, OH can be produced from the photo-dissociation of H2O through H2O + γUV OH + H.

Methods. High-resolution spectroscopy of the 163.12 μm triplet of OH towards HH 46 and NGC 1333 IRAS 2A was carried out with the Heterodyne Instrument for the Far Infrared (HIFI) on board the Herschel Space Observatory. The low- and intermediate-mass protostars HH 46, TMR 1, IRAS 15398-3359, DK Cha, NGC 7129 FIRS 2, and NGC 1333 IRAS 2A were observed with the Photodetector Array Camera and Spectrometer (PACS) on Herschel in four transitions of OH and two [O i] lines.

Results. The OH transitions at 79, 84, 119, and 163 μm and [O i] emission at 63 and 145μm were detected with PACS towards the class I low-mass YSOs as well as the intermediate-mass and class I Herbig Ae sources. No OH emission was detected from the class 0 YSO NGC 1333 IRAS 2A, though the 119 μm was detected in absorption. With HIFI, the 163.12 μm was not detected from HH 46 and only tentatively detected from NGC 1333 IRAS 2A. The combination of the PACS and HIFI results for HH 46 constrains the line width (FWHM 11 km s-1) and indicates that the OH emission likely originates from shocked gas. This scenario is supported by trends of the OH flux increasing with the [O i] flux and the bolometric luminosity, as found in our sample. Similar OH line ratios for most sources suggest that OH has comparable excitation temperatures despite the different physical properties of the sources.
 
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  Call Number Serial (down) 1103  
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Author Melnick, G. J.; Tolls, V.; Neufeld, D. A.; Bergin, E. A.; Phillips, T. G.; Wang, S.; Crockett, N. R.; Bell, T. A.; Blake, G. A.; Cabrit, S.; Caux, E.; Ceccarelli, C.; Cernicharo, J.; Comito, C.; Daniel, F.; Dubernet, M.-L.; Emprechtinger, M.; Encrenaz, P.; Falgarone, E.; Gerin, M.; Giesen, T. F.; Goicoechea, J. R.; Goldsmith, P. F.; Herbst, E.; Joblin, C.; Johnstone, D.; Langer, W. D.; Latter, W. D.; Lis, D. C.; Lord, S. D.; Maret, S.; Martin, P. G.; Menten, K. M.; Morris, P.; Müller, H. S. P.; Murphy, J. A.; Ossenkopf, V.; Pagani, L.; Pearson, J. C.; Pérault, M.; Plume, R.; Qin, S.-L.; Salez, M.; Schilke, P.; Schlemmer, S.; Stutzki, J.; Trappe, N.; van der Tak, F. F. S.; Vastel, C.; Yorke, H. W.; Yu, S.; Zmuidzinas, J. doi  openurl
  Title Herschel observations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L27  
  Keywords HEB mixer applications, HIFI, Herschel, ISM: abundances / ISM: molecules  
  Abstract We report the detection of more than 48 velocity-resolved ground rotational state transitions of H216O, H218O, and H217O – most for the first time – in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H218O line fluxes, which are less affected by line opacity than their H216O counterparts, and an escape probability method, the column densities of H218O associated with each emission component are derived. We infer total water abundances of 7.4 × 10-5, 1.0 × 10-5, and 1.6 × 10-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources.  
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  Notes Approved no  
  Call Number Serial (down) 1098  
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Author Justtanont, K.; Decin, L.; Schöier, F. L.; Maercker, M.; Olofsson, H.; Bujarrabal, V.; Marston, A. P.; Teyssier, D.; Alcolea, J.; Cernicharo, J.; Dominik, C.; de Koter, A.; Melnick, G.; Menten, K.; Neufeld, D.; Planesas, P.; Schmidt, M.; Szczerba, R.; Waters, R.; de Graauw, Th.; Whyborn, N.; Finn, T.; Helmich, F.; Siebertz, O.; Schmülling, F.; Ossenkopf, V.; Lai, R. doi  openurl
  Title A HIFI preview of warm molecular gas around χ Cygni: first detection of H2O emission toward an S-type AGB star Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L6  
  Keywords HEB mixer applications, HIFI, Herschel, stars: AGB and post-AGB / circumstellar matter / stars: kinematics and dynamics / stars: individual: χ Cyg / stars: late-type / stars: mass-loss  
  Abstract Aims. A set of new, sensitive, and spectrally resolved, sub-millimeter line observations are used to probe the warm circumstellar gas around the S-type AGB star χ Cyg. The observed lines involve high rotational quantum numbers, which, combined with previously obtained lower-frequency data, make it possible to study in detail the chemical and physical properties of, essentially, the entire circumstellar envelope of χ Cyg.

Methods. The data were obtained using the HIFI instrument aboard Herschel, whose high spectral resolution provides valuable information about the line profiles. Detailed, non-LTE, radiative transfer modelling, including dust radiative transfer coupled with a dynamical model, has been performed to derive the temperature, density, and velocity structure of the circumstellar envelope.

Results. We report the first detection of circumstellar H2O rotational emission lines in an S-star. Using the high-J CO lines to derive the parameters for the circumstellar envelope, we modelled both the ortho- and para-H2O lines. Our modelling results are consistent with the velocity structure expected for a dust-driven wind. The derived total H2O abundance (relative to H2) is (1.1±0.2) × 10-5, much lower than that in O-rich stars. The derived ortho-to-para ratio of 2.1±0.6 is close to the high-temperature equilibrium limit, consistent with H2O being formed in the photosphere.
 
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  Notes Approved no  
  Call Number Serial (down) 1096  
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Author Maret, S.; Bacmann, A.; Bottinelli, S.; Parise, B.; Caux, E.; Faure, A.; Bergin, E. A.; Blake, G. A.; Castets, A.; Ceccarelli, C.; Cernicharo, J.; Coutens, A.; Crimier, N.; Demyk, K.; Dominik, C.; Gerin, M.; Hennebelle, P.; Henning, T.; Kahane, C.; Klotz, A.; Melnick, G.; Pagani, L.; Schilke, P.; Vastel, C.; Wakelam, V.; Walters, A.; Baudry, A.; Bell, T.; Benedettini, M.; Boogert, A.; Cabrit, S.; Caselli, P.; Codella, C.; Comito, C.; Encrenaz, P.; Falgarone, E.; Fuente, A.; Goldsmith, P. F.; Helmich, F.; Herbst, E.; Jacq, T.; Kama, M.; Langer, W.; Lefloch, B.; Lis, D.; Lord, S.; Lorenzani, A.; Neufeld, D.; Nisini, B.; Pacheco, S.; Phillips, T.; Salez, M.; Saraceno, P.; Schuster, K.; Tielens, X.; van der Tak, F.; van der Wiel, M. H. D.; Viti, S.; Wyrowski, F.; Yorke, H. doi  openurl
  Title Nitrogen hydrides in the cold envelope of IRAS 16293-2422 Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L52  
  Keywords HEB mixer applications, HIFI, Herschel, ISM: abundances / ISM: general / astrochemistry  
  Abstract Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes.  
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  Notes Approved no  
  Call Number Serial (down) 1094  
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Author De Luca, M.; Gupta, H.; Neufeld, D.; Gerin, M.; Teyssier, D.; Drouin, B. J.; Pearson, J. C.; Lis, D. C.; Monje, R.; Phillips, T. G.; Goicoechea, J. R.; Godard, B.; Falgarone, E.; Coutens, A.; Bell, T. A. doi  openurl
  Title Herschel/HIFI discovery of HCL+ in the interstellar medium Type Journal Article
  Year 2012 Publication Astrophys. J. Lett. Abbreviated Journal  
  Volume 751 Issue 2 Pages L37  
  Keywords HEB mixer applications, HIFI, Herschel  
  Abstract The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models.  
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  Notes Approved no  
  Call Number Serial (down) 1092  
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