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Author |
Рябчун, С. А. |
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Title |
Широкополосные высокостабильные терагерцовые смесители на горячих электронах из тонких сверхпроводниковых пленок NbN |
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Year |
2009 |
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М. МПГУ |
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98 |
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HEB, mixer, terahertz, THz, stability, Allan variance, conversion bandwidth, in-situ technique, Au contacts |
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Ph.D. thesis |
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598 |
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Ryabchun, S. A.; Tretyakov, I. V.; Finkel, M. I.; Maslennikov, S. N.; Kaurova, N. S.; Seleznev, V. A.; Voronov, B. M.; Gol'tsman, G. N. |
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Title |
NbN phonon-cooled hot-electron bolometer mixer with additional diffusion cooling |
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Conference Article |
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2009 |
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Proc. 20th Int. Symp. Space Terahertz Technol. |
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Proc. 20th ISSTT |
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151-154 |
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HEB, mixer, bandwidth, noise temperatue, in-situ contacts, in situ contacts |
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Charlottesville, USA |
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590 |
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Treuttel, J.; Thomas, B.; Maestrini, A.; Wang, H.; Alderman, B.; Siles, J.V.; Davis, S.; Narhi, T. |
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A 380 GHz sub-harmonic mixer using MMIC foundry based Schottky diodes transferred onto quartz substrate |
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Conference Article |
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2009 |
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Proc. 20th Int. Symp. Space Terahertz Technol. |
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Schottky |
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Charlottesville, Virginia, USA |
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586 |
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Минаева, Ольга Вячеславовна |
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Title |
Быстродействующий однофотонный детектор на основе тонкой сверхпроводниковой пленки NbN |
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2009 |
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М. МПГУ |
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SSPD |
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Ph.D. thesis |
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russian |
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585 |
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Parrott, Edward P. J.; Zeitler, J. Axel; Fris<cc><152>c<cc><152>ic<cc><81>, Tomislav; Pepper, Michael; Jones, William; Day, Graeme M.; Gladden, Lynn F. |
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Title |
Testing the sensitivity of terahertz spectroscopy to changes in molecular and supramolecular structure: a study of structurally similar cocrystals |
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Journal Article |
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2009 |
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Crystal Growth & Design |
Abbreviated Journal |
Crystal Growth & Design |
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9 |
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3 |
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1452-1460 |
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Keywords |
supramolecular recognition, infrared, terahertz, IR, THz, TDS |
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Terahertz time-domain-spectroscopy (THz-TDS) has emerged as a versatile spectroscopic technique, and an alternative to powder X-ray diffraction in the characterization of molecular crystals. We tested the ability of terahertz spectroscopy to distinguish between chiral and racemic hydrogen-bonded cocrystals that are similar in molecular and supramolecular structure. Terahertz spectroscopy readily distinguished between the isostructural cocrystals of theophylline with chiral and racemic forms of malic acid which are almost identical in molecular structure and supramolecular architecture. Similarly, the cocrystals of theophylline with chiral and racemic forms of tartaric acid, which are similar at the molecular level but dissimilar in crystal packing, were distinguished unequivocally. The investigation of the same cocrystals using X-ray powder diffraction and Raman spectroscopy suggested that THz-TDS is comparable in sensitivity to diffraction methods and more sensitive than Raman spectroscopy to changes in cocrystal architecture. The differences in spectra acquired by THz-TDS could be further enhanced by cooling the samples to 109 K. |
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1528-7483 |
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567 |
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