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De Luca, M.; Gupta, H.; Neufeld, D.; Gerin, M.; Teyssier, D.; Drouin, B. J.; Pearson, J. C.; Lis, D. C.; Monje, R.; Phillips, T. G.; Goicoechea, J. R.; Godard, B.; Falgarone, E.; Coutens, A.; Bell, T. A. |
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Herschel/HIFI discovery of HCL+ in the interstellar medium |
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2012 |
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Astrophys. J. Lett. |
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751 |
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2 |
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L37 |
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HEB mixer applications, HIFI, Herschel |
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The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models. |
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1092 |
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Hartogh, P.; Jarchow, C.; Lellouch, E.; de Val-Borro, M.; Rengel, M.; Moreno, R.; Medvedev, A. S.; Sagawa, H.; Swinyard, B. M.; Cavalié, T.; Lis, D. C.; BłÄ™cka, M. I.; Banaszkiewicz, M.; Bockelée-Morvan, D.; Crovisier, J.; Encrenaz, T.; Küppers, M.; Lara, L.-M.; Szutowicz, S.; Vandenbussche, B.; Bensch, F.; Bergin, E. A.; Billebaud, F.; Biver, N.; Blake, G. A.; Blommaert, J. A. D. L.; Cernicharo, J.; Decin, L.; Encrenaz, P.; Feuchtgruber, H.; Fulton, T.; de Graauw, T.; Jehin, E.; Kidger, M.; Lorente, R.; Naylor, D. A.; Portyankina, G.; Sánchez-Portal, M.; Schieder, R.; Sidher, S.; Thomas, N.; Verdugo, E.; Waelkens, C.; Whyborn, N.; Teyssier, D.; Helmich, F.; Roelfsema, P.; Stutzki, J.; LeDuc, H. G.; Stern, J. A. |
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Herschel/HIFI observations of Mars: First detection of O2 at submillimetre wavelengths and upper limits on HCl and H2O2 |
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2010 |
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Astron. Astrophys. |
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521 |
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L49 |
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HEB mixer applications, HIFI, Herschel, planets and satellites: atmospheres / radiative transfer / submillimeter: general / molecular processes |
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We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements. |
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1093 |
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Hartogh, P.; Crovisier, J.; de Val-Borro, M.; Bockelée-Morvan, D.; Biver, N.; Lis, D. C.; Moreno, R.; Jarchow, C.; Rengel, M.; Emprechtinger, M.; Szutowicz, S.; Banaszkiewicz, M.; Bensch, F.; Blecka, M. I.; Cavalié, T.; Encrenaz, T.; Jehin, E.; Küppers, M.; Lara, L.-M.; Lellouch, E.; Swinyard, B. M.; Vandenbussche, B.; Bergin, E. A.; Blake, G. A.; Blommaert, J. A. D. L.; Cernicharo, J.; Decin, L.; Encrenaz, P.; de Graauw, T.; Hutsemekers, D.; Kidger, M.; Manfroid, J.; Medvedev, A. S.; Naylor, D. A.; Schieder, R.; Thomas, N.; Waelkens, C.; Roelfsema, P. R.; Dieleman, P.; Güsten, R.; Klein, T.; Kasemann, C.; Caris, M.; Olberg, M.; Benz, A. O. |
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HIFI observations of water in the atmosphere of comet C/2008 Q3 (Garradd) |
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Journal Article |
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2010 |
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Astron. Astrophys. |
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518 |
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L150 (1 to 5) |
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HEB mixer applications, HIFI, Herschel, comets: individual: C/2008 Q3 / radio lines: general / submillimeter: general / techniques: spectroscopic |
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High-resolution far-infrared and sub-millimetre spectroscopy of water lines is an important tool to understand the physical and chemical properties of cometary atmospheres. We present observations of several rotational ortho- and para-water transitions in comet C/2008 Q3 (Garradd) performed with HIFI on Herschel. These observations have provided the first detection of the 212–101 (1669 GHz) ortho and 111–000 (1113 GHz) para transitions of water in a cometary spectrum. In addition, the ground-state transition 110–101 at 557 GHz is detected and mapped. By detecting several water lines quasi-simultaneously and mapping their emission we can constrain the excitation parameters in the coma. Synthetic line profiles are computed using excitation models which include excitation by collisions, solar infrared radiation, and radiation trapping. We obtain the gas kinetic temperature, constrain the electron density profile, and estimate the coma expansion velocity by analyzing the map and line shapes. We derive water production rates of 1.7–2.8 × 1028 s-1 over the range rh = 1.83–1.85 AU. |
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1088 |
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Benz, A. O.; Bruderer, S.; van Dishoeck, E. F.; Stäuber, P.; Wampfler, S. F.; Melchior, M.; Dedes, C.; Wyrowski, F.; Doty, S. D.; van der Tak, F.; Bächtold, W.; Csillaghy, A.; Megej, A.; Monstein, C.; Soldati, M.; Bachiller, R.; Baudry, A.; Benedettini, M.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bontemps, S.; Braine, J.; Caselli, P.; Cernicharo, J.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dieleman, P.; Dominik, C.; Encrenaz, P.; Fich, M.; Fuente, A.; Giannini, T.; Goicoechea, J. R.; de Graauw, Th.; Helmich, F.; Herczeg, G. J.; Herpin, F.; Hogerheijde, M. R.; Jacq, T.; Jellema, W.; Johnstone, D.; Jørgensen, J. K.; Kristensen, L. E.; Larsson, B.; Lis, D.; Liseau, R.; Marseille, M.; McCoey, C.; Melnick, G.; Neufeld, D.; Nisini, B.; Olberg, M.; Ossenkopf, V.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-García, J.; Saraceno, P.; Schieder, R.; Shipman, R.; Stutzki, J.; Tafalla, M.; Tielens, A. G. G. M.; van Kempen, T. A.; Visser, R.; Yıldız, U. A. |
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Hydrides in young stellar objects: Radiation tracers in a protostar-disk-outflow system |
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Journal Article |
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2010 |
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Astron. Astrophys. |
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521 |
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L35 (1 to 5) |
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HEB mixer applications, HIFI, Herschel |
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Context. Hydrides of the most abundant heavier elements are fundamental molecules in cosmic chemistry. Some of them trace gas irradiated by UV or X-rays.
Aims. We explore the abundances of major hydrides in W3 IRS5, a prototypical region of high-mass star formation.
Methods. W3 IRS5 was observed by HIFI on the Herschel Space Observatory with deep integration (2500 s) in 8 spectral regions.
Results. The target lines including CH, NH, H3O+, and the new molecules SH+, H2O+, and OH+ are detected. The H2O+ and OH+ J = 1–0 lines are found mostly in absorption, but also appear to exhibit weak emission (P-Cyg-like). Emission requires high density, thus originates most likely near the protostar. This is corroborated by the absence of line shifts relative to the young stellar object (YSO). In addition, H2O+ and OH+ also contain strong absorption components at a velocity shifted relative to W3 IRS5, which are attributed to foreground clouds.
Conclusions. The molecular column densities derived from observations correlate well with the predictions of a model that assumes the main emission region is in outflow walls, heated and irradiated by protostellar UV radiation. |
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1082 |
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Maret, S.; Bacmann, A.; Bottinelli, S.; Parise, B.; Caux, E.; Faure, A.; Bergin, E. A.; Blake, G. A.; Castets, A.; Ceccarelli, C.; Cernicharo, J.; Coutens, A.; Crimier, N.; Demyk, K.; Dominik, C.; Gerin, M.; Hennebelle, P.; Henning, T.; Kahane, C.; Klotz, A.; Melnick, G.; Pagani, L.; Schilke, P.; Vastel, C.; Wakelam, V.; Walters, A.; Baudry, A.; Bell, T.; Benedettini, M.; Boogert, A.; Cabrit, S.; Caselli, P.; Codella, C.; Comito, C.; Encrenaz, P.; Falgarone, E.; Fuente, A.; Goldsmith, P. F.; Helmich, F.; Herbst, E.; Jacq, T.; Kama, M.; Langer, W.; Lefloch, B.; Lis, D.; Lord, S.; Lorenzani, A.; Neufeld, D.; Nisini, B.; Pacheco, S.; Phillips, T.; Salez, M.; Saraceno, P.; Schuster, K.; Tielens, X.; van der Tak, F.; van der Wiel, M. H. D.; Viti, S.; Wyrowski, F.; Yorke, H. |
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Nitrogen hydrides in the cold envelope of IRAS 16293-2422 |
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Journal Article |
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2010 |
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Astron. Astrophys. |
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521 |
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L52 |
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HEB mixer applications, HIFI, Herschel, ISM: abundances / ISM: general / astrochemistry |
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Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes. |
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