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Hartogh P, Jarchow C, Lellouch E, de Val-Borro M, Rengel M, Moreno R, et al. Herschel/HIFI observations of Mars: First detection of O2 at submillimetre wavelengths and upper limits on HCl and H2O2. Astron. Astrophys.. 2010;521:L49.
Abstract: We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements.
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Bruderer S, Benz AO, van Dishoeck EF, Melchior M, Doty SD, van der Tak F, et al. Herschel/HIFI detections of hydrides towards AFGL 2591. Envelope emission versus tenuous cloud absorption. Astron. Astrophys.. 2010;521:L44 (1 to 7).
Abstract: The Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory allows the first observations of light diatomic molecules at high spectral resolution and in multiple transitions. Here, we report deep integrations using HIFI in different lines of hydrides towards the high-mass star forming region AFGL 2591. Detected are CH, CH+, NH, OH+, H2O+, while NH+ and SH+ have not been detected. All molecules except for CH and CH+ are seen in absorption with low excitation temperatures and at velocities different from the systemic velocity of the protostellar envelope. Surprisingly, the CH(JF,P = 3/22,- – 1/21,+ ) and CH+(J = 1–0, J = 2–1) lines are detected in emission at the systemic velocity. We can assign the absorption features to a foreground cloud and an outflow lobe, while the CH and CH+ emission stems from the envelope. The observed abundance and excitation of CH and CH+ can be explained in the scenario of FUV irradiated outflow walls, where a cavity etched out by the outflow allows protostellar FUV photons to irradiate and heat the envelope at larger distances driving the chemical reactions that produce these molecules.
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Justtanont K, Decin L, Schöier FL, Maercker M, Olofsson H, Bujarrabal V, et al. A HIFI preview of warm molecular gas around χ Cygni: first detection of H2O emission toward an S-type AGB star. Astron. Astrophys.. 2010;521:L6.
Abstract: Aims. A set of new, sensitive, and spectrally resolved, sub-millimeter line observations are used to probe the warm circumstellar gas around the S-type AGB star χ Cyg. The observed lines involve high rotational quantum numbers, which, combined with previously obtained lower-frequency data, make it possible to study in detail the chemical and physical properties of, essentially, the entire circumstellar envelope of χ Cyg.
Methods. The data were obtained using the HIFI instrument aboard Herschel, whose high spectral resolution provides valuable information about the line profiles. Detailed, non-LTE, radiative transfer modelling, including dust radiative transfer coupled with a dynamical model, has been performed to derive the temperature, density, and velocity structure of the circumstellar envelope.
Results. We report the first detection of circumstellar H2O rotational emission lines in an S-star. Using the high-J CO lines to derive the parameters for the circumstellar envelope, we modelled both the ortho- and para-H2O lines. Our modelling results are consistent with the velocity structure expected for a dust-driven wind. The derived total H2O abundance (relative to H2) is (1.1±0.2) × 10-5, much lower than that in O-rich stars. The derived ortho-to-para ratio of 2.1±0.6 is close to the high-temperature equilibrium limit, consistent with H2O being formed in the photosphere.
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de Graauw T, Caux E, Guesten R, Helmich F, Pearson J, Phillips TG, et al. The Herschel-heterodyne instrument for the far-infrared (HIFI). In: Bulletin of the American Astronomical Society.; 2005. 1219. (Bulletin of the American Astronomical Society; vol 37).
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Wild W, de Graauw T, Baryshev A, Bos A, Gao JR, Gunst A, et al. Terahertz technology for ESPRIT – a far-infrared space interferometer. In: Proc. 16th Int. Symp. Space Terahertz Technol. Göteborg, Sweden; 2005.
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