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Wampfler SF, Herczeg GJ, Bruderer S, Benz AO, van Dishoeck EF, Kristensen LE, et al. Herschel observations of the hydroxyl radical (OH) in young stellar objects. Astron. Astrophys.. 2010;521:L36.
Abstract: Aims. “Water In Star-forming regions with Herschel†(WISH) is a Herschel key program investigating the water chemistry in young stellar objects (YSOs) during protostellar evolution. Hydroxyl (OH) is one of the reactants in the chemical network most closely linked to the formation and destruction of H2O. High-temperature (T 250 K) chemistry connects OH and H2O through the OH + H2 H2O + H reactions. Formation of H2O from OH is efficient in the high-temperature regime found in shocks and the innermost part of protostellar envelopes. Moreover, in the presence of UV photons, OH can be produced from the photo-dissociation of H2O through H2O + γUV OH + H.
Methods. High-resolution spectroscopy of the 163.12 μm triplet of OH towards HH 46 and NGC 1333 IRAS 2A was carried out with the Heterodyne Instrument for the Far Infrared (HIFI) on board the Herschel Space Observatory. The low- and intermediate-mass protostars HH 46, TMR 1, IRAS 15398-3359, DK Cha, NGC 7129 FIRS 2, and NGC 1333 IRAS 2A were observed with the Photodetector Array Camera and Spectrometer (PACS) on Herschel in four transitions of OH and two [O i] lines.
Results. The OH transitions at 79, 84, 119, and 163 μm and [O i] emission at 63 and 145μm were detected with PACS towards the class I low-mass YSOs as well as the intermediate-mass and class I Herbig Ae sources. No OH emission was detected from the class 0 YSO NGC 1333 IRAS 2A, though the 119 μm was detected in absorption. With HIFI, the 163.12 μm was not detected from HH 46 and only tentatively detected from NGC 1333 IRAS 2A. The combination of the PACS and HIFI results for HH 46 constrains the line width (FWHM 11 km s-1) and indicates that the OH emission likely originates from shocked gas. This scenario is supported by trends of the OH flux increasing with the [O i] flux and the bolometric luminosity, as found in our sample. Similar OH line ratios for most sources suggest that OH has comparable excitation temperatures despite the different physical properties of the sources.
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Mookerjea B, Giesen T, Stutzki J, Cernicharo J, Goicoechea JR, De Luca M, et al. Excitation and abundance of C3 in star forming cores. Herschel/HIFI observations of the sight-lines to W31C and W49N. Astron. Astrophys.. 2010;521:L13.
Abstract: We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy ν2 bending mode at frequencies between 1654–1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (Trot) of ~50-70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived Trot, we get column densities N(C3) ~ 7–9 × 1014 cm-2 and abundance x(C3) ~ 10-8 with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3) = 10-8, Tkin = 30–50 K, N(C3) = 1.5 × 1015 cm-2 fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis.
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Melnick GJ, Tolls V, Neufeld DA, Bergin EA, Phillips TG, Wang S, et al. Herschel observations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL. Astron. Astrophys.. 2010;521:L27.
Abstract: We report the detection of more than 48 velocity-resolved ground rotational state transitions of H216O, H218O, and H217O – most for the first time – in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H218O line fluxes, which are less affected by line opacity than their H216O counterparts, and an escape probability method, the column densities of H218O associated with each emission component are derived. We infer total water abundances of 7.4 × 10-5, 1.0 × 10-5, and 1.6 × 10-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources.
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De Luca M, Gupta H, Neufeld D, Gerin M, Teyssier D, Drouin BJ, et al. Herschel/HIFI discovery of HCL+ in the interstellar medium. Astrophys. J. Lett.. 2012;751(2):L37.
Abstract: The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models.
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de Graauw T, Caux E, Guesten R, Helmich F, Pearson J, Phillips TG, et al. The Herschel-heterodyne instrument for the far-infrared (HIFI). In: Bulletin of the American Astronomical Society.; 2005. 1219. (Bulletin of the American Astronomical Society; vol 37).
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