Abstract: Context. In the past 15 years, several studies suggested that water in the stratosphere of Jupiter originated from the Shoemaker-Levy 9 (SL9) comet impacts in July 1994, but a direct proof was missing. Only a very sensitive instrument observing with high spectral/spatial resolution can help to solve this problem. This is the case of the Herschel Space Observatory, which is the first telescope capable of mapping water in Jupiter's stratosphere.
Aims. We observed the spatial distribution of the water emission in Jupiter's stratosphere with the Heterodyne Instrument for the Far Infrared (HIFI) and the Photodetector Array Camera and Spectrometer (PACS) onboard Herschel to constrain its origin. In parallel, we monitored Jupiter's stratospheric temperature with the NASA Infrared Telescope Facility (IRTF) to separate temperature from water variability.
Methods. We obtained a 25-point map of the 1669.9 GHz water line with HIFI in July 2010 and several maps with PACS in October 2009 and December 2010. The 2010 PACS map is a 400-point raster of the water 66.4 μm emission. Additionally, we mapped the methane ν4 band emission to constrain the stratospheric temperature in Jupiter in the same periods with the IRTF.
Results. Water is found to be restricted to pressures lower than 2 mbar. Its column density decreases by a factor of 2–3 between southern and northern latitudes, consistently between the HIFI and the PACS 66.4 μm maps. We infer that an emission maximum seen around 15 °S is caused by a warm stratospheric belt detected in the IRTF data.
Conclusions. Latitudinal temperature variability cannot explain the global north-south asymmetry in the water maps. From the latitudinal and vertical distributions of water in Jupiter's stratosphere, we rule out interplanetary dust particles as its main source. Furthermore, we demonstrate that Jupiter's stratospheric water was delivered by the SL9 comet and that more than 95% of the observed water comes from the comet according to our models.

Abstract: The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models.

Abstract: Aims. “Water In Star-forming regions with Herschel” (WISH) is a Herschel key program investigating the water chemistry in young stellar objects (YSOs) during protostellar evolution. Hydroxyl (OH) is one of the reactants in the chemical network most closely linked to the formation and destruction of H2O. High-temperature (T 250 K) chemistry connects OH and H2O through the OH + H2 H2O + H reactions. Formation of H2O from OH is efficient in the high-temperature regime found in shocks and the innermost part of protostellar envelopes. Moreover, in the presence of UV photons, OH can be produced from the photo-dissociation of H2O through H2O + γUV OH + H.
Methods. High-resolution spectroscopy of the 163.12 μm triplet of OH towards HH 46 and NGC 1333 IRAS 2A was carried out with the Heterodyne Instrument for the Far Infrared (HIFI) on board the Herschel Space Observatory. The low- and intermediate-mass protostars HH 46, TMR 1, IRAS 15398-3359, DK Cha, NGC 7129 FIRS 2, and NGC 1333 IRAS 2A were observed with the Photodetector Array Camera and Spectrometer (PACS) on Herschel in four transitions of OH and two [O i] lines.
Results. The OH transitions at 79, 84, 119, and 163 μm and [O i] emission at 63 and 145μm were detected with PACS towards the class I low-mass YSOs as well as the intermediate-mass and class I Herbig Ae sources. No OH emission was detected from the class 0 YSO NGC 1333 IRAS 2A, though the 119 μm was detected in absorption. With HIFI, the 163.12 μm was not detected from HH 46 and only tentatively detected from NGC 1333 IRAS 2A. The combination of the PACS and HIFI results for HH 46 constrains the line width (FWHM 11 km s-1) and indicates that the OH emission likely originates from shocked gas. This scenario is supported by trends of the OH flux increasing with the [O i] flux and the bolometric luminosity, as found in our sample. Similar OH line ratios for most sources suggest that OH has comparable excitation temperatures despite the different physical properties of the sources.