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De Luca, M.; Gupta, H.; Neufeld, D.; Gerin, M.; Teyssier, D.; Drouin, B. J.; Pearson, J. C.; Lis, D. C.; Monje, R.; Phillips, T. G.; Goicoechea, J. R.; Godard, B.; Falgarone, E.; Coutens, A.; Bell, T. A. |
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Title |
Herschel/HIFI discovery of HCL+ in the interstellar medium |
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Journal Article |
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2012 |
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Astrophys. J. Lett. |
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751 |
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2 |
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L37 |
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HEB mixer applications, HIFI, Herschel |
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The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models. |
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1092 |
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Hartogh, P.; Jarchow, C.; Lellouch, E.; de Val-Borro, M.; Rengel, M.; Moreno, R.; Medvedev, A. S.; Sagawa, H.; Swinyard, B. M.; Cavalié, T.; Lis, D. C.; BłÄ™cka, M. I.; Banaszkiewicz, M.; Bockelée-Morvan, D.; Crovisier, J.; Encrenaz, T.; Küppers, M.; Lara, L.-M.; Szutowicz, S.; Vandenbussche, B.; Bensch, F.; Bergin, E. A.; Billebaud, F.; Biver, N.; Blake, G. A.; Blommaert, J. A. D. L.; Cernicharo, J.; Decin, L.; Encrenaz, P.; Feuchtgruber, H.; Fulton, T.; de Graauw, T.; Jehin, E.; Kidger, M.; Lorente, R.; Naylor, D. A.; Portyankina, G.; Sánchez-Portal, M.; Schieder, R.; Sidher, S.; Thomas, N.; Verdugo, E.; Waelkens, C.; Whyborn, N.; Teyssier, D.; Helmich, F.; Roelfsema, P.; Stutzki, J.; LeDuc, H. G.; Stern, J. A. |
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Title |
Herschel/HIFI observations of Mars: First detection of O2 at submillimetre wavelengths and upper limits on HCl and H2O2 |
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Journal Article |
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2010 |
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Astron. Astrophys. |
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521 |
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L49 |
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HEB mixer applications, HIFI, Herschel, planets and satellites: atmospheres / radiative transfer / submillimeter: general / molecular processes |
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We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements. |
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1093 |
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Maret, S.; Bacmann, A.; Bottinelli, S.; Parise, B.; Caux, E.; Faure, A.; Bergin, E. A.; Blake, G. A.; Castets, A.; Ceccarelli, C.; Cernicharo, J.; Coutens, A.; Crimier, N.; Demyk, K.; Dominik, C.; Gerin, M.; Hennebelle, P.; Henning, T.; Kahane, C.; Klotz, A.; Melnick, G.; Pagani, L.; Schilke, P.; Vastel, C.; Wakelam, V.; Walters, A.; Baudry, A.; Bell, T.; Benedettini, M.; Boogert, A.; Cabrit, S.; Caselli, P.; Codella, C.; Comito, C.; Encrenaz, P.; Falgarone, E.; Fuente, A.; Goldsmith, P. F.; Helmich, F.; Herbst, E.; Jacq, T.; Kama, M.; Langer, W.; Lefloch, B.; Lis, D.; Lord, S.; Lorenzani, A.; Neufeld, D.; Nisini, B.; Pacheco, S.; Phillips, T.; Salez, M.; Saraceno, P.; Schuster, K.; Tielens, X.; van der Tak, F.; van der Wiel, M. H. D.; Viti, S.; Wyrowski, F.; Yorke, H. |
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Title |
Nitrogen hydrides in the cold envelope of IRAS 16293-2422 |
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Journal Article |
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Year |
2010 |
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Astron. Astrophys. |
Abbreviated Journal |
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521 |
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L52 |
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HEB mixer applications, HIFI, Herschel, ISM: abundances / ISM: general / astrochemistry |
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Abstract |
Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes. |
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1094 |
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Melnick, G. J.; Tolls, V.; Neufeld, D. A.; Bergin, E. A.; Phillips, T. G.; Wang, S.; Crockett, N. R.; Bell, T. A.; Blake, G. A.; Cabrit, S.; Caux, E.; Ceccarelli, C.; Cernicharo, J.; Comito, C.; Daniel, F.; Dubernet, M.-L.; Emprechtinger, M.; Encrenaz, P.; Falgarone, E.; Gerin, M.; Giesen, T. F.; Goicoechea, J. R.; Goldsmith, P. F.; Herbst, E.; Joblin, C.; Johnstone, D.; Langer, W. D.; Latter, W. D.; Lis, D. C.; Lord, S. D.; Maret, S.; Martin, P. G.; Menten, K. M.; Morris, P.; Müller, H. S. P.; Murphy, J. A.; Ossenkopf, V.; Pagani, L.; Pearson, J. C.; Pérault, M.; Plume, R.; Qin, S.-L.; Salez, M.; Schilke, P.; Schlemmer, S.; Stutzki, J.; Trappe, N.; van der Tak, F. F. S.; Vastel, C.; Yorke, H. W.; Yu, S.; Zmuidzinas, J. |
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Title |
Herschel observations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL |
Type |
Journal Article |
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Year |
2010 |
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Astron. Astrophys. |
Abbreviated Journal |
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521 |
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L27 |
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HEB mixer applications, HIFI, Herschel, ISM: abundances / ISM: molecules |
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Abstract |
We report the detection of more than 48 velocity-resolved ground rotational state transitions of H216O, H218O, and H217O – most for the first time – in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H218O line fluxes, which are less affected by line opacity than their H216O counterparts, and an escape probability method, the column densities of H218O associated with each emission component are derived. We infer total water abundances of 7.4 × 10-5, 1.0 × 10-5, and 1.6 × 10-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources. |
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1098 |
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Mookerjea, B.; Giesen, T.; Stutzki, J.; Cernicharo, J.; Goicoechea, J. R.; De Luca, M.; Bell, T. A.; Gupta, H.; Gerin, M.; Persson, C. M.; Sonnentrucker, P.; Makai, Z.; Black, J.; Boulanger, F.; Coutens, A.; Dartois, E.; Encrenaz, P.; Falgarone, E.; Geballe, T.; Godard, B.; Goldsmith, P. F.; Gry, C.; Hennebelle, P.; Herbst, E.; Hily-Blant, P.; Joblin, C.; Ka<c5><ba>mierczak, M.; Kołos, R.; Krełowski, J.; Lis, D. C.; Martin-Pintado, J.; Menten, K. M.; Monje, R.; Pearson, J. C.; Perault, M.; Phillips, T. G.; Plume, R.; Salez, M.; Schlemmer, S.; Schmidt, M.; Teyssier, D.; Vastel, C.; Yu, S.; Dieleman, P.; Güsten, R.; Honingh, C. E.; Morris, P.; Roelfsema, P.; Schieder, R.; Tielens, A. G. G. M.; Zmuidzinas, J. |
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Title |
Excitation and abundance of C3 in star forming cores. Herschel/HIFI observations of the sight-lines to W31C and W49N |
Type |
Journal Article |
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2010 |
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Astron. Astrophys. |
Abbreviated Journal |
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521 |
Issue |
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Pages |
L13 |
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HEB mixer applications, HIFI, Herschel, ISM: lines and bands / ISM: molecules / radiative transfer / ISM: individual objects: W49N / ISM: individual objects: W31C |
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Abstract |
We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy ν2 bending mode at frequencies between 1654–1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (Trot) of ~50-70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived Trot, we get column densities N(C3) ~ 7–9 × 1014 cm-2 and abundance x(C3) ~ 10-8 with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3) = 10-8, Tkin = 30–50 K, N(C3) = 1.5 × 1015 cm-2 fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis. |
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1099 |
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