Mookerjea B, Giesen T, Stutzki J, Cernicharo J, Goicoechea JR, De Luca M, et al. Excitation and abundance of C3 in star forming cores. Herschel/HIFI observations of the sight-lines to W31C and W49N. Astron. Astrophys.. 2010;521:L13.
Abstract: We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy ν2 bending mode at frequencies between 1654–1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (Trot) of ~50-70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived Trot, we get column densities N(C3) ~ 7–9 × 1014 cm-2 and abundance x(C3) ~ 10-8 with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3) = 10-8, Tkin = 30–50 K, N(C3) = 1.5 × 1015 cm-2 fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis.
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Melnick GJ, Tolls V, Neufeld DA, Bergin EA, Phillips TG, Wang S, et al. Herschel observations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL. Astron. Astrophys.. 2010;521:L27.
Abstract: We report the detection of more than 48 velocity-resolved ground rotational state transitions of H216O, H218O, and H217O – most for the first time – in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H218O line fluxes, which are less affected by line opacity than their H216O counterparts, and an escape probability method, the column densities of H218O associated with each emission component are derived. We infer total water abundances of 7.4 × 10-5, 1.0 × 10-5, and 1.6 × 10-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources.
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Crockett NR, Bergin EA, Wang S, Lis DC, Bell TA, Blake GA, et al. Herschel observations of EXtra-Ordinary Sources (HEXOS): The Terahertz spectrum of Orion KL seen at high spectral resolution. Annual Rev. Astron. Astrophys.. 2010;521:L21 (1 to 5).
Abstract: We present the first high spectral resolution observations of Orion KL in the frequency ranges 1573.4–1702.8 GHz (band 6b) and 1788.4–1906.8 GHz (band 7b) obtained using the HIFI instrument on board the Herschel Space Observatory. We characterize the main emission lines found in the spectrum, which primarily arise from a range of components associated with Orion KL including the hot core, but also see widespread emission from components associated with molecular outflows traced by H2O, SO2, and OH. We find that the density of observed emission lines is significantly diminished in these bands compared to lower frequency Herschel/HIFI bands.
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Maret S, Bacmann A, Bottinelli S, Parise B, Caux E, Faure A, et al. Nitrogen hydrides in the cold envelope of IRAS 16293-2422. Astron. Astrophys.. 2010;521:L52.
Abstract: Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes.
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