Abstract: Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes.

Abstract: Context. In the past 15 years, several studies suggested that water in the stratosphere of Jupiter originated from the Shoemaker-Levy 9 (SL9) comet impacts in July 1994, but a direct proof was missing. Only a very sensitive instrument observing with high spectral/spatial resolution can help to solve this problem. This is the case of the Herschel Space Observatory, which is the first telescope capable of mapping water in Jupiter's stratosphere.
Aims. We observed the spatial distribution of the water emission in Jupiter's stratosphere with the Heterodyne Instrument for the Far Infrared (HIFI) and the Photodetector Array Camera and Spectrometer (PACS) onboard Herschel to constrain its origin. In parallel, we monitored Jupiter's stratospheric temperature with the NASA Infrared Telescope Facility (IRTF) to separate temperature from water variability.
Methods. We obtained a 25-point map of the 1669.9 GHz water line with HIFI in July 2010 and several maps with PACS in October 2009 and December 2010. The 2010 PACS map is a 400-point raster of the water 66.4 μm emission. Additionally, we mapped the methane ν4 band emission to constrain the stratospheric temperature in Jupiter in the same periods with the IRTF.
Results. Water is found to be restricted to pressures lower than 2 mbar. Its column density decreases by a factor of 2–3 between southern and northern latitudes, consistently between the HIFI and the PACS 66.4 μm maps. We infer that an emission maximum seen around 15 °S is caused by a warm stratospheric belt detected in the IRTF data.
Conclusions. Latitudinal temperature variability cannot explain the global north-south asymmetry in the water maps. From the latitudinal and vertical distributions of water in Jupiter's stratosphere, we rule out interplanetary dust particles as its main source. Furthermore, we demonstrate that Jupiter's stratospheric water was delivered by the SL9 comet and that more than 95% of the observed water comes from the comet according to our models.

Abstract: The Spectral and Photometric Imaging REceiver (SPIRE), is the Herschel Space Observatory`s submillimetre camera and spectrometer. It contains a three-band imaging photometer operating at 250, 350 and 500 μm, and an imaging Fourier-transform spectrometer (FTS) which covers simultaneously its whole operating range of 194-671 μm (447-1550 GHz). The SPIRE detectors are arrays of feedhorn-coupled bolometers cooled to 0.3 K. The photometer has a field of view of 4Â´× 8´, observed simultaneously in the three spectral bands. Its main operating mode is scan-mapping, whereby the field of view is scanned across the sky to achieve full spatial sampling and to cover large areas if desired. The spectrometer has an approximately circular field of view with a diameter of 2.6´. The spectral resolution can be adjusted between 1.2 and 25 GHz by changing the stroke length of the FTS scan mirror. Its main operating mode involves a fixed telescope pointing with multiple scans of the FTS mirror to acquire spectral data. For extended source measurements, multiple position offsets are implemented by means of an internal beam steering mirror to achieve the desired spatial sampling and by rastering of the telescope pointing to map areas larger than the field of view. The SPIRE instrument consists of a cold focal plane unit located inside the Herschel cryostat and warm electronics units, located on the spacecraft Service Module, for instrument control and data handling. Science data are transmitted to Earth with no on-board data compression, and processed by automatic pipelines to produce calibrated science products. The in-flight performance of the instrument matches or exceeds predictions based on pre-launch testing and modelling: the photometer sensitivity is comparable to or slightly better than estimated pre-launch, and the spectrometer sensitivity is also better by a factor of 1.5-2.