Bruderer S, Benz AO, van Dishoeck EF, Melchior M, Doty SD, van der Tak F, et al. Herschel/HIFI detections of hydrides towards AFGL 2591. Envelope emission versus tenuous cloud absorption. Astron. Astrophys.. 2010;521:L44 (1 to 7).
Abstract: The Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory allows the first observations of light diatomic molecules at high spectral resolution and in multiple transitions. Here, we report deep integrations using HIFI in different lines of hydrides towards the high-mass star forming region AFGL 2591. Detected are CH, CH+, NH, OH+, H2O+, while NH+ and SH+ have not been detected. All molecules except for CH and CH+ are seen in absorption with low excitation temperatures and at velocities different from the systemic velocity of the protostellar envelope. Surprisingly, the CH(JF,P = 3/22,- – 1/21,+ ) and CH+(J = 1–0, J = 2–1) lines are detected in emission at the systemic velocity. We can assign the absorption features to a foreground cloud and an outflow lobe, while the CH and CH+ emission stems from the envelope. The observed abundance and excitation of CH and CH+ can be explained in the scenario of FUV irradiated outflow walls, where a cavity etched out by the outflow allows protostellar FUV photons to irradiate and heat the envelope at larger distances driving the chemical reactions that produce these molecules.
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Maret S, Bacmann A, Bottinelli S, Parise B, Caux E, Faure A, et al. Nitrogen hydrides in the cold envelope of IRAS 16293-2422. Astron. Astrophys.. 2010;521:L52.
Abstract: Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes.
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de Graauw T, Caux E, Guesten R, Helmich F, Pearson J, Phillips TG, et al. The Herschel-heterodyne instrument for the far-infrared (HIFI). In: Bulletin of the American Astronomical Society.; 2005. 1219. (Bulletin of the American Astronomical Society; vol 37).
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Decin L, Justtanont K, De Beck E, Lombaert R, de Koter A, Waters LBFM, et al. Water content and wind acceleration in the envelope around the oxygen-rich AGB star IK Tauri as seen by Herschel/HIFI. Astron. Astrophys.. 2010;521:L4.
Abstract: During their asymptotic giant branch evolution, low-mass stars lose a significant fraction of their mass through an intense wind, enriching the interstellar medium with products of nucleosynthesis. We observed the nearby oxygen-rich asymptotic giant branch star IK Tau using the high-resolution HIFI spectrometer onboard Herschel. We report on the first detection of H216O and the rarer isotopologues H217O and H218O in both the ortho and para states. We deduce a total water content (relative to molecular hydrogen) of $6.6 \times 10^{-5}$, and an ortho-to-para ratio of 3:1. These results are consistent with the formation of H2O in thermodynamical chemical equilibrium at photospheric temperatures, and does not require pulsationally induced non-equilibrium chemistry, vaporization of icy bodies or grain surface reactions. High-excitation lines of 12CO, 13CO, 28SiO, 29SiO, 30SiO, HCN, and SO have also been detected. From the observed line widths, the acceleration region in the inner wind zone can be characterized, and we show that the wind acceleration is slower than hitherto anticipated.
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