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Parrott EPJ, Zeitler JA, Fris<cc><152>c<cc><152>ic<cc><81> T, Pepper M, Jones W, Day GM, et al. Testing the sensitivity of terahertz spectroscopy to changes in molecular and supramolecular structure: a study of structurally similar cocrystals. Crystal Growth & Design. 2009;9(3):1452–60.
Abstract: Terahertz time-domain-spectroscopy (THz-TDS) has emerged as a versatile spectroscopic technique, and an alternative to powder X-ray diffraction in the characterization of molecular crystals. We tested the ability of terahertz spectroscopy to distinguish between chiral and racemic hydrogen-bonded cocrystals that are similar in molecular and supramolecular structure. Terahertz spectroscopy readily distinguished between the isostructural cocrystals of theophylline with chiral and racemic forms of malic acid which are almost identical in molecular structure and supramolecular architecture. Similarly, the cocrystals of theophylline with chiral and racemic forms of tartaric acid, which are similar at the molecular level but dissimilar in crystal packing, were distinguished unequivocally. The investigation of the same cocrystals using X-ray powder diffraction and Raman spectroscopy suggested that THz-TDS is comparable in sensitivity to diffraction methods and more sensitive than Raman spectroscopy to changes in cocrystal architecture. The differences in spectra acquired by THz-TDS could be further enhanced by cooling the samples to 109 K.
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Lobanov Y, Shcherbatenko M, Shurakov A, Rodin AV, Klimchuk A, Nadezhdinsky AI, et al. Heterodyne detection at near-infrared wavelengths with a superconducting NbN hot-electron bolometer mixer. Opt. Lett.. 2014;39(6):1429–32.
Abstract: We report on the development of a highly sensitive optical receiver for heterodyne IR spectroscopy at the communication wavelength of 1.5 μm (200 THz) by use of a superconducting hot-electron bolometer. The results are important for the resolution of narrow spectral molecular lines in the near-IR range for the study of astronomical objects, as well as for quantum optical tomography and fiber-optic sensing. Receiver configuration as well as fiber-to-detector light coupling designs are discussed. Light absorption of the superconducting detectors was enhanced by nano-optical antennas, which were coupled to optical fibers. An intermediate frequency (IF) bandwidth of about 3 GHz was found in agreement with measurements at 300 GHz, and a noise figure of about 25 dB was obtained that was only 10 dB above the quantum limit.
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Soifer BT, Pipher JL. Instrumentation for infrared astronomy. Annual Rev. Astron. Astrophys.. 1978;16(1):335–69.
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Teich MC. Infrared heterodyne detection. In: Proc. IEEE. Vol 56. IEEE; 1968. p. 37–46.
Abstract: Heterodyne experiments have been performed in the middle infrared region of the electromagnetic spectrum using the CO2laser as a radiation source. Theoretically optimum operation has been achieved at kHz heterodyne frequencies using photoconductive Ge:Cu detectors operated at 4°K, and at kHz and MHz frequencies using Pb1-xSnxSe photovoltaic detectors at 77°K. In accordance with the theory, the minimum detectable power observed is a factor of 2/η greater than the theoretically perfect quantum counter, hvΔf. The coefficient 2/η varies from 5 to 25 for the detectors investigated in this study. A comparison is made between photoconductive and photodiode detectors for heterodyne use in the infrared, and it is concluded that both are useful. Heterodyne detection at 10.6 µm is expected to be useful for communications applications, infrared radar, and heterodyne spectroscopy. It has particular significance because of the high radiation power available from the CO2laser, and because of the 8 to 14 µm atmospheric window.
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Gershenson ME, Gong D, Sato T, Karasik BS, Sergeev AV. Millisecond electron-phonon relaxation in ultrathin disordered metal films at millikelvin temperatures. Appl. Phys. Lett.. 2001;79:2049–51.
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