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Author (up) Benz, A. O.; Bruderer, S.; van Dishoeck, E. F.; Stäuber, P.; Wampfler, S. F.; Melchior, M.; Dedes, C.; Wyrowski, F.; Doty, S. D.; van der Tak, F.; Bächtold, W.; Csillaghy, A.; Megej, A.; Monstein, C.; Soldati, M.; Bachiller, R.; Baudry, A.; Benedettini, M.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bontemps, S.; Braine, J.; Caselli, P.; Cernicharo, J.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dieleman, P.; Dominik, C.; Encrenaz, P.; Fich, M.; Fuente, A.; Giannini, T.; Goicoechea, J. R.; de Graauw, Th.; Helmich, F.; Herczeg, G. J.; Herpin, F.; Hogerheijde, M. R.; Jacq, T.; Jellema, W.; Johnstone, D.; Jørgensen, J. K.; Kristensen, L. E.; Larsson, B.; Lis, D.; Liseau, R.; Marseille, M.; McCoey, C.; Melnick, G.; Neufeld, D.; Nisini, B.; Olberg, M.; Ossenkopf, V.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-García, J.; Saraceno, P.; Schieder, R.; Shipman, R.; Stutzki, J.; Tafalla, M.; Tielens, A. G. G. M.; van Kempen, T. A.; Visser, R.; Yıldız, U. A. doi  openurl
  Title Hydrides in young stellar objects: Radiation tracers in a protostar-disk-outflow system Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L35 (1 to 5)  
  Keywords HEB mixer applications, HIFI, Herschel  
  Abstract Context. Hydrides of the most abundant heavier elements are fundamental molecules in cosmic chemistry. Some of them trace gas irradiated by UV or X-rays.

Aims. We explore the abundances of major hydrides in W3 IRS5, a prototypical region of high-mass star formation.

Methods. W3 IRS5 was observed by HIFI on the Herschel Space Observatory with deep integration (2500 s) in 8 spectral regions.

Results. The target lines including CH, NH, H3O+, and the new molecules SH+, H2O+, and OH+ are detected. The H2O+ and OH+ J = 1–0 lines are found mostly in absorption, but also appear to exhibit weak emission (P-Cyg-like). Emission requires high density, thus originates most likely near the protostar. This is corroborated by the absence of line shifts relative to the young stellar object (YSO). In addition, H2O+ and OH+ also contain strong absorption components at a velocity shifted relative to W3 IRS5, which are attributed to foreground clouds.

Conclusions. The molecular column densities derived from observations correlate well with the predictions of a model that assumes the main emission region is in outflow walls, heated and irradiated by protostellar UV radiation.
 
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  Notes Approved no  
  Call Number Serial 1082  
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Author (up) Bruderer, S.; Benz, A. O.; van Dishoeck, E. F.; Melchior, M.; Doty, S. D.; van der Tak, F.; Stäuber, P.; Wampfler, S. F.; Dedes, C.; Yıldız, U. A.; Pagani, L.; Giannini, T.; de Graauw, Th.; Whyborn, N.; Teyssier, D.; Jellema, W.; Shipman, R.; Schieder, R.; Honingh, N.; Caux, E.; Bächtold, W.; Csillaghy, A.; Monstein, C.; Bachiller, R.; Baudry, A.; Benedettini, M.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bontemps, S.; Braine, J.; Caselli, P.; Cernicharo, J.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dominik, C.; Encrenaz, P.; Fich, M.; Fuente, A.; Goicoechea, J. R.; Helmich, F.; Herczeg, G. J.; Herpin, F.; Hogerheijde, M. R.; Jacq, T.; Johnstone, D.; Jørgensen, J. K.; Kristensen, L. E.; Larsson, B.; Lis, D.; Liseau, R.; Marseille, M.; McCoey, C.; Melnick, G.; Neufeld, D.; Nisini, B.; Olberg, M.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-García, J.; Saraceno, P.; Shipman, R.; Tafalla, M.; van Kempen, T. A.; Visser, R.; Wyrowski, F. doi  openurl
  Title Herschel/HIFI detections of hydrides towards AFGL 2591. Envelope emission versus tenuous cloud absorption Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L44 (1 to 7)  
  Keywords HEB mixer applications, HIFI, Herschel  
  Abstract The Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory allows the first observations of light diatomic molecules at high spectral resolution and in multiple transitions. Here, we report deep integrations using HIFI in different lines of hydrides towards the high-mass star forming region AFGL 2591. Detected are CH, CH+, NH, OH+, H2O+, while NH+ and SH+ have not been detected. All molecules except for CH and CH+ are seen in absorption with low excitation temperatures and at velocities different from the systemic velocity of the protostellar envelope. Surprisingly, the CH(JF,P = 3/22,- – 1/21,+ ) and CH+(J = 1–0, J = 2–1) lines are detected in emission at the systemic velocity. We can assign the absorption features to a foreground cloud and an outflow lobe, while the CH and CH+ emission stems from the envelope. The observed abundance and excitation of CH and CH+ can be explained in the scenario of FUV irradiated outflow walls, where a cavity etched out by the outflow allows protostellar FUV photons to irradiate and heat the envelope at larger distances driving the chemical reactions that produce these molecules.  
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  Notes Approved no  
  Call Number Serial 1083  
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Author (up) Bujarrabal, V.; Alcolea, J.; Soria-Ruiz, R.; Planesas, P.; Teyssier, D.; Marston, A. P.; Cernicharo, J.; Decin, L.; Dominik, C.; Justtanont, K.; de Koter, A.; Melnick, G.; Menten, K. M.; Neufeld, D. A.; Olofsson, H.; Schmidt, M.; Schöier, F. L.; Szczerba, R.; Waters, L. B. F. M.; Quintana-Lacaci, G.; Güsten, R.; Gallego, J. D.; Díez-González, M. C.; Barcia, A.; López-Fernández, I.; Wildeman, K.; Tielens, A. G. G. M.; Jacobs, K. doi  openurl
  Title Herschel/HIFI observations of high-J CO transitions in the protoplanetary nebula CRL 618 Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L3 (1 to 5)  
  Keywords HEB mixer applications, HIFI, Herschel  
  Abstract Aims. We aim to study the physical conditions, particularly the excitation state, of the intermediate-temperature gas components in the protoplanetary nebula CRL 618. These components are particularly important for understanding the evolution of the nebula.

Methods. We performed Herschel/HIFI observations of several CO lines in the far-infrared/sub-mm in the protoplanetary nebula CRL 618. The high spectral resolution provided by HIFI allows measurement of the line profiles. Since the dynamics and structure of the nebula is well known from mm-wave interferometric maps, it is possible to identify the contributions of the different nebular components (fast bipolar outflows, double shells, compact slow shell) to the line profiles. The observation of these relatively high-energy transitions allows an accurate study of the excitation conditions in these components, particularly in the warm ones, which cannot be properly studied from the low-energy lines.

Results. The 12CO J = 16–15, 10–9, and 6–5 lines are easily detected in this source. Both 13CO J = 10–9 and 6–5 are also detected. Wide profiles showing spectacular line wings have been found, particularly in 12CO J = 16–15. Other lines observed simultaneously with CO are also shown. Our analysis of the CO high-J transitions, when compared with the existing models, confirms the very low expansion velocity of the central, dense component, which probably indicates that the shells ejected during the last AGB phases were driven by radiation pressure under a regime of maximum transfer of momentum. No contribution of the diffuse halo found from mm-wave data is identified in our spectra, because of its low temperature. We find that the fast bipolar outflow is quite hot, much hotter than previously estimated; for instance, gas flowing at 100 km s-1 must have a temperature higher than ~200 K. Probably, this very fast outflow, with a kinematic age <100 yr, has been accelerated by a shock and has not yet cooled down. The double empty shell found from mm-wave mapping must also be relatively hot, in agreement with the previous estimate.
 
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  Notes Approved no  
  Call Number Serial 1084  
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Author (up) Chavarr'ıa, L.; Herpin, F.; Jacq, T.; Braine, J.; Bontemps, S.; Baudry, A.; Marseille, M.; van der Tak, F.; Pietropaoli, B.; Wyrowski, F.; Shipman, R.; Frieswijk, W.; van Dishoeck, E. F.; Cernicharo, J.; Bachiller, R.; Benedettini, M.; Benz, A. O.; Bergin, E.; Bjerkeli, P.; Blake, G. A.; Bruderer, S.; Caselli, P.; Codella, C.; Daniel, F.; di Giorgio, A. M.; Dominik, C.; Doty, S. D.; Encrenaz, P.; Fich, M.; Fuente, A.; Giannini, T.; Goicoechea, J. R.; de Graauw, T.; Hartogh, P.; Helmich, F.; Herczeg, G. J.; Hogerheijde, M. R.; Johnstone, D.; Jørgensen, J. K.; Kristensen, L. E.; Larsson, B.; Lis, D.; Liseau, R.; McCoey, C.; Melnick, G.; Nisini, B.; Olberg, M.; Parise, B.; Pearson, J. C.; Plume, R.; Risacher, C.; Santiago-Garc'ıa, J.; Saraceno, P.; Stutzki, J.; Szczerba, R.; Tafalla, M.; Tielens, A.; van Kempen, T. A.; Visser, R.; Wampfler, S. F.; Willem, J.; Yıldız, U. A. doi  openurl
  Title Water in massive star-forming regions: HIFI observations of W3 IRS5 Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L37 (1 to 5)  
  Keywords HEB mixer applications, HIFI, Herschel, stars: formation, stars: massive, ISM: molecules, ISM: abundances, dust, extinction, radio lines: ISM  
  Abstract We present Herschel observations of the water molecule in the massive star-forming region W3 IRS5. The o-H217O 110-101, p-H218O 111-000, p-H2O 202-111, p-H2O 111-000, o-H2O 221-212, and o-H2O 212-101 lines, covering a frequency range from 552 up to 1669 GHz, have been detected at high spectral resolution with HIFI. The water lines in W3 IRS5 show well-defined high-velocity wings that indicate a clear contribution by outflows. Moreover, the systematically blue-shifted absorption in the H2O lines suggests expansion, presumably driven by the outflow. No infall signatures are detected. The p-H2O 111-000 and o-H2O 212-101 lines show absorption from the cold material (T ~ 10 K) in which the high-mass protostellar envelope is embedded. One-dimensional radiative transfer models are used to estimate water abundances and to further study the kinematics of the region. We show that the emission in the rare isotopologues comes directly from the inner parts of the envelope (T â‰<b3> 100 K) where water ices in the dust mantles evaporate and the gas-phase abundance increases. The resulting jump in the water abundance (with a constant inner abundance of 10-4) is needed to reproduce the o-H217O 110-101 and p-H218O 111-000 spectra in our models. We estimate water abundances of 10-8 to 10-9 in the outer parts of the envelope (T â‰<b2> 100 K). The possibility of two protostellar objects contributing to the emission is discussed.  
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  Notes Approved no  
  Call Number Chav13HEBapplHIFIb Serial 1086  
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Author (up) Crockett, N. R.; Bergin, E. A.; Wang, S.; Lis, D. C.; Bell, T. A.; Blake, G. A.; Boogert, A.; Bumble, B.; Cabrit, S.; Caux, E.; Ceccarelli, C.; Cernicharo, J.; Comito, C.; Daniel, F.; Dubernet, M.-L.; Emprechtinger, M.; Encrenaz, P.; Falgarone, E.; Gerin, M.; Giesen, T. F.; Goicoechea, J. R.; Goldsmith, P. F.; Gupta, H.; Güsten, R.; Hartogh, P.; Helmich, F.; Herbst, E.; Honingh, N.; Joblin, C.; Johnstone, D.; Karpov, A.; Kawamura, J. H.; Kooi, J.; Krieg, J.-M.; Langer, W. D.; Latter, W. D.; Lord, S. D.; Maret, S.; Martin, P. G.; Melnick, G. J.; Menten, K. M.; Morris, P.; Müller, H. S. P.; Murphy, J. A.; Neufeld, D. A.; Ossenkopf, V.; Pearson, J. C.; Pérault, M.; Phillips, T. G.; Plume, R.; Qin, S.-L.; Roelfsema, P.; Schieder, R.; Schilke, P.; Schlemmer, S.; Stutzki, J.; van der Tak, F. F. S.; Tielens, A.; Trappe, N.; Vastel, C.; Yorke, H. W.; Yu, S.; Zmuidzinas, J. doi  openurl
  Title Herschel observations of EXtra-Ordinary Sources (HEXOS): The Terahertz spectrum of Orion KL seen at high spectral resolution Type Journal Article
  Year 2010 Publication Annual Rev. Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L21 (1 to 5)  
  Keywords HEB mixer applications, HIFI, Herschel  
  Abstract We present the first high spectral resolution observations of Orion KL in the frequency ranges 1573.4–1702.8 GHz (band 6b) and 1788.4–1906.8 GHz (band 7b) obtained using the HIFI instrument on board the Herschel Space Observatory. We characterize the main emission lines found in the spectrum, which primarily arise from a range of components associated with Orion KL including the hot core, but also see widespread emission from components associated with molecular outflows traced by H2O, SO2, and OH. We find that the density of observed emission lines is significantly diminished in these bands compared to lower frequency Herschel/HIFI bands.  
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  Notes Approved no  
  Call Number Serial 1087  
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Author (up) Decin, L.; Justtanont, K.; De Beck, E.; Lombaert, R.; de Koter, A.; Waters, L. B. F. M.; Marston, A. P.; Teyssier, D.; Schöier, F. L.; Bujarrabal, V.; Alcolea, J.; Cernicharo, J.; Dominik, C.; Melnick, G.; Menten, K.; Neufeld, D. A.; Olofsson, H.; Planesas, P.; Schmidt, M.; Szczerba, R.; de Graauw, T.; Helmich, F.; Roelfsema, P.; Dieleman, P.; Morris, P.; Gallego, J. D.; Díez-González, M. C.; Caux, E. doi  openurl
  Title Water content and wind acceleration in the envelope around the oxygen-rich AGB star IK Tauri as seen by Herschel/HIFI Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L4  
  Keywords HEB mixer applications, HIFI, Herschel, line: profiles / radiative transfer / instrumentation: spectrographs / stars: AGB and post-AGB / circumstellar matter / submillimeter: stars  
  Abstract During their asymptotic giant branch evolution, low-mass stars lose a significant fraction of their mass through an intense wind, enriching the interstellar medium with products of nucleosynthesis. We observed the nearby oxygen-rich asymptotic giant branch star IK Tau using the high-resolution HIFI spectrometer onboard Herschel. We report on the first detection of H216O and the rarer isotopologues H217O and H218O in both the ortho and para states. We deduce a total water content (relative to molecular hydrogen) of $6.6 \times 10^{-5}$, and an ortho-to-para ratio of 3:1. These results are consistent with the formation of H2O in thermodynamical chemical equilibrium at photospheric temperatures, and does not require pulsationally induced non-equilibrium chemistry, vaporization of icy bodies or grain surface reactions. High-excitation lines of 12CO, 13CO, 28SiO, 29SiO, 30SiO, HCN, and SO have also been detected. From the observed line widths, the acceleration region in the inner wind zone can be characterized, and we show that the wind acceleration is slower than hitherto anticipated.  
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  Notes Approved no  
  Call Number Serial 1090  
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Author (up) Hartogh, P.; Crovisier, J.; de Val-Borro, M.; Bockelée-Morvan, D.; Biver, N.; Lis, D. C.; Moreno, R.; Jarchow, C.; Rengel, M.; Emprechtinger, M.; Szutowicz, S.; Banaszkiewicz, M.; Bensch, F.; Blecka, M. I.; Cavalié, T.; Encrenaz, T.; Jehin, E.; Küppers, M.; Lara, L.-M.; Lellouch, E.; Swinyard, B. M.; Vandenbussche, B.; Bergin, E. A.; Blake, G. A.; Blommaert, J. A. D. L.; Cernicharo, J.; Decin, L.; Encrenaz, P.; de Graauw, T.; Hutsemekers, D.; Kidger, M.; Manfroid, J.; Medvedev, A. S.; Naylor, D. A.; Schieder, R.; Thomas, N.; Waelkens, C.; Roelfsema, P. R.; Dieleman, P.; Güsten, R.; Klein, T.; Kasemann, C.; Caris, M.; Olberg, M.; Benz, A. O. doi  openurl
  Title HIFI observations of water in the atmosphere of comet C/2008 Q3 (Garradd) Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 518 Issue Pages L150 (1 to 5)  
  Keywords HEB mixer applications, HIFI, Herschel, comets: individual: C/2008 Q3 / radio lines: general / submillimeter: general / techniques: spectroscopic  
  Abstract High-resolution far-infrared and sub-millimetre spectroscopy of water lines is an important tool to understand the physical and chemical properties of cometary atmospheres. We present observations of several rotational ortho- and para-water transitions in comet C/2008 Q3 (Garradd) performed with HIFI on Herschel. These observations have provided the first detection of the 212–101 (1669 GHz) ortho and 111–000 (1113 GHz) para transitions of water in a cometary spectrum. In addition, the ground-state transition 110–101 at 557 GHz is detected and mapped. By detecting several water lines quasi-simultaneously and mapping their emission we can constrain the excitation parameters in the coma. Synthetic line profiles are computed using excitation models which include excitation by collisions, solar infrared radiation, and radiation trapping. We obtain the gas kinetic temperature, constrain the electron density profile, and estimate the coma expansion velocity by analyzing the map and line shapes. We derive water production rates of 1.7–2.8 × 1028 s-1 over the range rh = 1.83–1.85 AU.  
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  Notes Approved no  
  Call Number Serial 1088  
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Author (up) Hartogh, P.; Jarchow, C.; Lellouch, E.; de Val-Borro, M.; Rengel, M.; Moreno, R.; Medvedev, A. S.; Sagawa, H.; Swinyard, B. M.; Cavalié, T.; Lis, D. C.; BłÄ™cka, M. I.; Banaszkiewicz, M.; Bockelée-Morvan, D.; Crovisier, J.; Encrenaz, T.; Küppers, M.; Lara, L.-M.; Szutowicz, S.; Vandenbussche, B.; Bensch, F.; Bergin, E. A.; Billebaud, F.; Biver, N.; Blake, G. A.; Blommaert, J. A. D. L.; Cernicharo, J.; Decin, L.; Encrenaz, P.; Feuchtgruber, H.; Fulton, T.; de Graauw, T.; Jehin, E.; Kidger, M.; Lorente, R.; Naylor, D. A.; Portyankina, G.; Sánchez-Portal, M.; Schieder, R.; Sidher, S.; Thomas, N.; Verdugo, E.; Waelkens, C.; Whyborn, N.; Teyssier, D.; Helmich, F.; Roelfsema, P.; Stutzki, J.; LeDuc, H. G.; Stern, J. A. doi  openurl
  Title Herschel/HIFI observations of Mars: First detection of O2 at submillimetre wavelengths and upper limits on HCl and H2O2 Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L49  
  Keywords HEB mixer applications, HIFI, Herschel, planets and satellites: atmospheres / radiative transfer / submillimeter: general / molecular processes  
  Abstract We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements.  
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  Notes Approved no  
  Call Number Serial 1093  
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Author (up) Justtanont, K.; Decin, L.; Schöier, F. L.; Maercker, M.; Olofsson, H.; Bujarrabal, V.; Marston, A. P.; Teyssier, D.; Alcolea, J.; Cernicharo, J.; Dominik, C.; de Koter, A.; Melnick, G.; Menten, K.; Neufeld, D.; Planesas, P.; Schmidt, M.; Szczerba, R.; Waters, R.; de Graauw, Th.; Whyborn, N.; Finn, T.; Helmich, F.; Siebertz, O.; Schmülling, F.; Ossenkopf, V.; Lai, R. doi  openurl
  Title A HIFI preview of warm molecular gas around χ Cygni: first detection of H2O emission toward an S-type AGB star Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L6  
  Keywords HEB mixer applications, HIFI, Herschel, stars: AGB and post-AGB / circumstellar matter / stars: kinematics and dynamics / stars: individual: χ Cyg / stars: late-type / stars: mass-loss  
  Abstract Aims. A set of new, sensitive, and spectrally resolved, sub-millimeter line observations are used to probe the warm circumstellar gas around the S-type AGB star χ Cyg. The observed lines involve high rotational quantum numbers, which, combined with previously obtained lower-frequency data, make it possible to study in detail the chemical and physical properties of, essentially, the entire circumstellar envelope of χ Cyg.

Methods. The data were obtained using the HIFI instrument aboard Herschel, whose high spectral resolution provides valuable information about the line profiles. Detailed, non-LTE, radiative transfer modelling, including dust radiative transfer coupled with a dynamical model, has been performed to derive the temperature, density, and velocity structure of the circumstellar envelope.

Results. We report the first detection of circumstellar H2O rotational emission lines in an S-star. Using the high-J CO lines to derive the parameters for the circumstellar envelope, we modelled both the ortho- and para-H2O lines. Our modelling results are consistent with the velocity structure expected for a dust-driven wind. The derived total H2O abundance (relative to H2) is (1.1±0.2) × 10-5, much lower than that in O-rich stars. The derived ortho-to-para ratio of 2.1±0.6 is close to the high-temperature equilibrium limit, consistent with H2O being formed in the photosphere.
 
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  Notes Approved no  
  Call Number Serial 1096  
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Author (up) Maret, S.; Bacmann, A.; Bottinelli, S.; Parise, B.; Caux, E.; Faure, A.; Bergin, E. A.; Blake, G. A.; Castets, A.; Ceccarelli, C.; Cernicharo, J.; Coutens, A.; Crimier, N.; Demyk, K.; Dominik, C.; Gerin, M.; Hennebelle, P.; Henning, T.; Kahane, C.; Klotz, A.; Melnick, G.; Pagani, L.; Schilke, P.; Vastel, C.; Wakelam, V.; Walters, A.; Baudry, A.; Bell, T.; Benedettini, M.; Boogert, A.; Cabrit, S.; Caselli, P.; Codella, C.; Comito, C.; Encrenaz, P.; Falgarone, E.; Fuente, A.; Goldsmith, P. F.; Helmich, F.; Herbst, E.; Jacq, T.; Kama, M.; Langer, W.; Lefloch, B.; Lis, D.; Lord, S.; Lorenzani, A.; Neufeld, D.; Nisini, B.; Pacheco, S.; Phillips, T.; Salez, M.; Saraceno, P.; Schuster, K.; Tielens, X.; van der Tak, F.; van der Wiel, M. H. D.; Viti, S.; Wyrowski, F.; Yorke, H. doi  openurl
  Title Nitrogen hydrides in the cold envelope of IRAS 16293-2422 Type Journal Article
  Year 2010 Publication Astron. Astrophys. Abbreviated Journal  
  Volume 521 Issue Pages L52  
  Keywords HEB mixer applications, HIFI, Herschel, ISM: abundances / ISM: general / astrochemistry  
  Abstract Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS 16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78 THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8 THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3 â‰<2c6> 5:1:300. Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes.  
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  ISSN ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number Serial 1094  
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