Abstract: We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy ν2 bending mode at frequencies between 1654–1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (Trot) of ~50-70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived Trot, we get column densities N(C3) ~ 7–9 × 1014 cm-2 and abundance x(C3) ~ 10-8 with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3) = 10-8, Tkin = 30–50 K, N(C3) = 1.5 × 1015 cm-2 fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis.

Abstract: Using Herschel's HIFI instrument, we observe C ii along a cut through S140, as well as high-J transitions of CO and HCO+ at two positions on the cut, corresponding to the externally irradiated ionization front and the embedded massive star-forming core IRS1. The HIFI data were combined with available ground-based observations and modeled using the KOSMA-Ï„ model for photon-dominated regions (PDRs). We derive the physical conditions in S140 and in particular the origin of C ii emission around IRS1. We identify three distinct regions of C ii emission from the cut, one close to the embedded source IRS1, one associated with the ionization front, and one further into the cloud. The line emission can be understood in terms of a clumpy model of PDRs. At the position of IRS1, we identify at least two distinct components contributing to the [C ii] emission, one of them a small, hot component, which can possibly be identified with the irradiated outflow walls. This is consistent with the C ii peak at IRS1 coinciding with shocked H2 emission at the edges of the outflow cavity. We note that previously available observations of IRS1 can be reproduced well by a single-component KOSMA-Ï„ model. Thus, it is HIFI's unprecedented spatial and spectral resolution, as well as its sensitivity that has allowed us to uncover an additional hot gas component in the S140 region.

Abstract: The Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory allows the first observations of light diatomic molecules at high spectral resolution and in multiple transitions. Here, we report deep integrations using HIFI in different lines of hydrides towards the high-mass star forming region AFGL 2591. Detected are CH, CH+, NH, OH+, H2O+, while NH+ and SH+ have not been detected. All molecules except for CH and CH+ are seen in absorption with low excitation temperatures and at velocities different from the systemic velocity of the protostellar envelope. Surprisingly, the CH(JF,P = 3/22,- – 1/21,+ ) and CH+(J = 1–0, J = 2–1) lines are detected in emission at the systemic velocity. We can assign the absorption features to a foreground cloud and an outflow lobe, while the CH and CH+ emission stems from the envelope. The observed abundance and excitation of CH and CH+ can be explained in the scenario of FUV irradiated outflow walls, where a cavity etched out by the outflow allows protostellar FUV photons to irradiate and heat the envelope at larger distances driving the chemical reactions that produce these molecules.