Hartogh, P., Jarchow, C., Lellouch, E., de Val-Borro, M., Rengel, M., Moreno, R., et al. (2010). Herschel/HIFI observations of Mars: First detection of O2 at submillimetre wavelengths and upper limits on HCl and H2O2. Astron. Astrophys., 521, L49.
Abstract: We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements.
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Bruderer, S., Benz, A. O., van Dishoeck, E. F., Melchior, M., Doty, S. D., van der Tak, F., et al. (2010). Herschel/HIFI detections of hydrides towards AFGL 2591. Envelope emission versus tenuous cloud absorption. Astron. Astrophys., 521, L44 (1 to 7).
Abstract: The Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory allows the first observations of light diatomic molecules at high spectral resolution and in multiple transitions. Here, we report deep integrations using HIFI in different lines of hydrides towards the high-mass star forming region AFGL 2591. Detected are CH, CH+, NH, OH+, H2O+, while NH+ and SH+ have not been detected. All molecules except for CH and CH+ are seen in absorption with low excitation temperatures and at velocities different from the systemic velocity of the protostellar envelope. Surprisingly, the CH(JF,P = 3/22,- – 1/21,+ ) and CH+(J = 1–0, J = 2–1) lines are detected in emission at the systemic velocity. We can assign the absorption features to a foreground cloud and an outflow lobe, while the CH and CH+ emission stems from the envelope. The observed abundance and excitation of CH and CH+ can be explained in the scenario of FUV irradiated outflow walls, where a cavity etched out by the outflow allows protostellar FUV photons to irradiate and heat the envelope at larger distances driving the chemical reactions that produce these molecules.
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De Luca, M., Gupta, H., Neufeld, D., Gerin, M., Teyssier, D., Drouin, B. J., et al. (2012). Herschel/HIFI discovery of HCL+ in the interstellar medium. Astrophys. J. Lett., 751(2), L37.
Abstract: The radical ion HCl+, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H35Cl+, 2Π3/2 J = 5/2-3/2, showing Λ-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl+. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H37Cl+ toward W31C, with a column density consistent with the expected 35Cl/37Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H2Cl+ yields an abundance ratio of unity with both species (HCl+ : H2Cl+ : HCl ~ 1). These observations also yield the unexpected result that HCl+ accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction (~1%) predicted by chemical models.
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Joblin, C., Pilleri, P., Montillaud, J., Fuente, A., Gerin, M., Berné, O., et al. (2010). Gas morphology and energetics at the surface of PDRs: New insights with Herschel observations of NGC 7023. Astron. Astrophys., 521, L25.
Abstract: Context. We investigate the physics and chemistry of the gas and dust in dense photon-dominated regions (PDRs), along with their dependence on the illuminating UV field.
Aims. Using Herschel/HIFI observations, we study the gas energetics in NGC 7023 in relation to the morphology of this nebula. NGC 7023 is the prototype of a PDR illuminated by a B2V star and is one of the key targets of Herschel.
Methods. Our approach consists in determining the energetics of the region by combining the information carried by the mid-IR spectrum (extinction by classical grains, emission from very small dust particles) with that of the main gas coolant lines. In this letter, we discuss more specifically the intensity and line profile of the 158 μm (1901 GHz) [C ii] line measured by HIFI and provide information on the emitting gas.
Results. We show that both the [C ii] emission and the mid-IR emission from polycyclic aromatic hydrocarbons (PAHs) arise from the regions located in the transition zone between atomic and molecular gas. Using the Meudon PDR code and a simple transfer model, we find good agreement between the calculated and observed [C ii] intensities.
Conclusions. HIFI observations of NGC 7023 provide the opportunity to constrain the energetics at the surface of PDRs. Future work will include analysis of the main coolant line [O i] and use of a new PDR model that includes PAH-related species.
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Dedes, C., Röllig, M., Mookerjea, B., Okada, Y., Ossenkopf, V., Bruderer, S., et al. (2010). The origin of the [C II] emission in the S140 photon-dominated regions. New insights from HIFI. Astron. Astrophys., 521, L24.
Abstract: Using Herschel's HIFI instrument, we observe C ii along a cut through S140, as well as high-J transitions of CO and HCO+ at two positions on the cut, corresponding to the externally irradiated ionization front and the embedded massive star-forming core IRS1. The HIFI data were combined with available ground-based observations and modeled using the KOSMA-Ï„ model for photon-dominated regions (PDRs). We derive the physical conditions in S140 and in particular the origin of C ii emission around IRS1. We identify three distinct regions of C ii emission from the cut, one close to the embedded source IRS1, one associated with the ionization front, and one further into the cloud. The line emission can be understood in terms of a clumpy model of PDRs. At the position of IRS1, we identify at least two distinct components contributing to the [C ii] emission, one of them a small, hot component, which can possibly be identified with the irradiated outflow walls. This is consistent with the C ii peak at IRS1 coinciding with shocked H2 emission at the edges of the outflow cavity. We note that previously available observations of IRS1 can be reproduced well by a single-component KOSMA-Ï„ model. Thus, it is HIFI's unprecedented spatial and spectral resolution, as well as its sensitivity that has allowed us to uncover an additional hot gas component in the S140 region.
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