Abstract: Aims. A set of new, sensitive, and spectrally resolved, sub-millimeter line observations are used to probe the warm circumstellar gas around the S-type AGB star χ Cyg. The observed lines involve high rotational quantum numbers, which, combined with previously obtained lower-frequency data, make it possible to study in detail the chemical and physical properties of, essentially, the entire circumstellar envelope of χ Cyg.
Methods. The data were obtained using the HIFI instrument aboard Herschel, whose high spectral resolution provides valuable information about the line profiles. Detailed, non-LTE, radiative transfer modelling, including dust radiative transfer coupled with a dynamical model, has been performed to derive the temperature, density, and velocity structure of the circumstellar envelope.
Results. We report the first detection of circumstellar H2O rotational emission lines in an S-star. Using the high-J CO lines to derive the parameters for the circumstellar envelope, we modelled both the ortho- and para-H2O lines. Our modelling results are consistent with the velocity structure expected for a dust-driven wind. The derived total H2O abundance (relative to H2) is (1.1±0.2) × 10-5, much lower than that in O-rich stars. The derived ortho-to-para ratio of 2.1±0.6 is close to the high-temperature equilibrium limit, consistent with H2O being formed in the photosphere.

Abstract: We report the detection of more than 48 velocity-resolved ground rotational state transitions of H216O, H218O, and H217O – most for the first time – in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H218O line fluxes, which are less affected by line opacity than their H216O counterparts, and an escape probability method, the column densities of H218O associated with each emission component are derived. We infer total water abundances of 7.4 × 10-5, 1.0 × 10-5, and 1.6 × 10-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources.

Abstract: The [C ii] fine-structure line at 158 μm is an excellent tracer of the warm diffuse gas in the ISM and the interfaces between molecular clouds and their surrounding atomic and ionized envelopes. Here we present the initial results from Galactic observations of terahertz C+ (GOT C+), a Herschel key project devoted to studying the [C ii] emission in the Galactic plane using the HIFI instrument. We used the [C ii] emission, together with observations of CO, as a probe to understand the effects of newly formed stars on their interstellar environment and characterize the physical and chemical state of the star-forming gas. We collected data along 16 lines-of-sight passing near star-forming regions in the inner Galaxy near longitudes 330° and 20°. We identified fifty-eight [C ii] components that are associated with high-column density molecular clouds as traced by 13CO emission. We combined [C ii], 12CO, and 13CO observations to derive the physical conditions of the [C ii]-emitting regions in our sample of high-column density clouds based on comparing results from a grid of photon dominated region (PDR) models. From this unbiased sample, our results suggest that most of the [C ii] emission originates in clouds with H2 volume densities between 103.5 and 105.5 cm-3 and weak FUV strength (χ0 = 1–10). We find two regions where our analysis suggest high densities >105 cm-3 and strong FUV fields (χ0 = 104–106), likely associated with massive star formation. We suggest that [C ii] emission in conjunction with CO isotopes is a good tool for differentiating regions of massive star formation (high densities/strong FUV fields) and regions that are distant from massive stars (lower densities/weaker FUV fields) along the line-of-sight.