PT Journal AU Hartogh, P Jarchow, C Lellouch, E de Val-Borro, M Rengel, M Moreno, R Medvedev, AS Sagawa, H Swinyard, BM Cavalié, T Lis, DC BłÄ™cka, MI Banaszkiewicz, M Bockelée-Morvan, D Crovisier, J Encrenaz, T Küppers, M Lara, L Szutowicz, S Vandenbussche, B Bensch, F Bergin, EA Billebaud, F Biver, N Blake, GA Blommaert, JADL Cernicharo, J Decin, L Encrenaz, P Feuchtgruber, H Fulton, T de Graauw, T Jehin, E Kidger, M Lorente, R Naylor, DA Portyankina, G Sánchez-Portal, M Schieder, R Sidher, S Thomas, N Verdugo, E Waelkens, C Whyborn, N Teyssier, D Helmich, F Roelfsema, P Stutzki, J LeDuc, HG Stern, JA TI Herschel/HIFI observations of Mars: First detection of O[sub:2] at submillimetre wavelengths and upper limits on HCl and H[sub:2]O[sub:2] SO Astron. Astrophys. PY 2010 BP L49 VL 521 DI 10.1051/0004-6361/201015160 DE HEB mixer applications; HIFI; Herschel; planets and satellites: atmospheres / radiative transfer / submillimeter: general / molecular processes AB We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H2O2), and molecular oxygen (O2) in the Martian atmosphere performed on 13 and 16 April 2010 (Ls ~ 77°). We derived a constant volume mixing ratio of 1400 ± 120 ppm for O2 and determined upper limits of 200 ppt for HCl and 2 ppb for H2O2. Radiative transfer model calculations indicate that the vertical profile of O2 may not be constant. Photochemical models determine the lowest values of H2O2 to be around Ls ~ 75° but overestimate the volume mixing ratio compared to our measurements. ER