TY - JOUR AU - Lieberzeit, P. AU - Afzal, A. AU - Rehman, A. AU - Dickert, F. PY - 2007 DA - 2007// TI - Nanoparticles for detecting pollutants and degradation processes with mass-sensitive sensors T2 - Sensors and Actuators B: Chemical JO - Sensors and Actuators B: Chemical SP - 132 EP - 136 VL - 127 IS - 1 KW - molecular imprinted polymer KW - MIP KW - recognition KW - quartz crystal microbalance KW - QCM KW - mass-sensitive sensor KW - detector AB - Compared with thin films, nanoparticle layers as coatings for QCM offer substantially increased interaction areas and sensitivities with favourable response times. Molybdenum disulphide (MoS2), e.g. has turned out to be a highly suitable material for interacting with thiols. The resulting materials are sufficiently soft according to Pearson to bind sulphur containing compounds reversibly. Depositing MoS2 nanoparticle submonolayers (particle size 200–300 nm) leads to an increase in sensor response by a factor of ten compared to a pure gold layer. Additionally, the nanoparticle layers show fully reversible sensor signals. Particle synthesis can also be combined with the molecular imprinting approach: by a precipitation technique, it is possible to generate molecularly imprinted TiO2 particles for engine oil degradation measurements. Compared with deposited thin layers, particles incorporate oxidised compounds from lubricants by a factor of two better. SN - 0925-4005 UR - http://linkinghub.elsevier.com/retrieve/pii/S0925400507004765 UR - https://doi.org/10.1016/j.snb.2007.07.020 DO - 10.1016/j.snb.2007.07.020 N1 - exported from refbase (https://db.rplab.ru/refbase/show.php?record=568), last updated on Thu, 19 Mar 2009 18:11:28 -0500 ID - Lieberzeit_etal2007 ER -