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Dickert, F. L., Haunschild, A., Kuschow, V., Reif, M., & Stathopulos, H. (1996). Mass-sensitive detection of solvent vapors. Mechanistic studies on host-guest sensor principles by FT-IR spectroscopy and BET adsorption analysis. Anal. Chem., 68(6), 1058–1061.
Abstract: Chemical sensors, based on highly mass sensitive QMB or SAW devices, coated with thin layers of calixarenes, enable the detection of organic solvent vapours, especially halogenated or aromatic hydrocarbons, down to a few ppm. Force field calculations allow the tailoring of these sensor materials seeing that the predicted interaction energies between the host molecules and a large variety of analytes are linearly correlated to the measured sensor effects. These correlations and also BET adsorption analysis prove the analyte recognition properties of these calixarene coatings to be mainly based on host/guest inclusion principles.
Keywords: supramolecular recognition, quartz crystal microbalance, QCM, surface acoustic wave, SAW, mass-sensitive sensor, detector, calixarenes, MM3 force field, Brunauer, Emmett and Teller theory, BET
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Rodriguez-Morales, F., Zannoni, R., Nicholson, J., Fischetti, M., Yngvesson, K. S., & Appenzeller, J. (2006). Direct and heterodyne detection of microwaves in a metallic single wall carbon nanotube. Appl. Phys. Lett., 89(8), 083502.
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Lieberzeit, P., Afzal, A., Rehman, A., & Dickert, F. (2007). Nanoparticles for detecting pollutants and degradation processes with mass-sensitive sensors. Sensors and Actuators B: Chemical, 127(1), 132–136.
Abstract: Compared with thin films, nanoparticle layers as coatings for QCM offer substantially increased interaction areas and sensitivities with favourable response times. Molybdenum disulphide (MoS2), e.g. has turned out to be a highly suitable material for interacting with thiols. The resulting materials are sufficiently soft according to Pearson to bind sulphur containing compounds reversibly. Depositing MoS2 nanoparticle submonolayers (particle size 200–300 nm) leads to an increase in sensor response by a factor of ten compared to a pure gold layer. Additionally, the nanoparticle layers show fully reversible sensor signals. Particle synthesis can also be combined with the molecular imprinting approach: by a precipitation technique, it is possible to generate molecularly imprinted TiO2 particles for engine oil degradation measurements. Compared with deposited thin layers, particles incorporate oxidised compounds from lubricants by a factor of two better.
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Kampfrath, T., Perfetti, L., von Volkmann, K., Aguirre, C. M., Desjardins, P., Martel, R., et al. (2007). Optical response of single-wall carbon nanotube sheets in the far-infrared spectral range from 1 THz to 40 THz. Phys. Stat. Sol. (B), 244(11), 3950–3954.
Abstract: The optical properties of single-wall carbon nanotube sheets in the far-infrared have been investigated with THz time-domain spectroscopy. Over a wide frequency range from 1 THz to 40 THz, the complex dielectric function of the nanotube sample has been derived. Our data can be excellently reproduced by a Drude-Lorentz model function. The extracted fit parameters such as Lorentz resonance frequency and plasma frequency are consistent with values obtained by scanning tunneling techniques. We discuss the origin of both the Lorentz and Drude contribution in terms of direct and indirect optical transitions.
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Kawano, Y., & Ishibashi, K. (2008). An on-chip near-field terahertz probe and detector. Nature Photon, 2(10), 618–621.
Abstract: The advantageous properties of terahertz waves, such as their transmission through objects opaque to visible light, are attracting attention for imaging applications. A promising approach for achieving high spatial resolution is the use of near-field imaging. Although this method has been well established in the visible and microwave regions, it is challenging to perform in the terahertz region. In the terahertz techniques investigated to date, detectors have been located remotely from the probe, which degrades sensitivity, and the influence of far-field waves is unavoidable. Here we present a new integrated detection device for terahertz near-field imaging in which all the necessary detection components — an aperture, a probe and a terahertz detector — are integrated on one semiconductor chip, which is cryogenically cooled. This scheme allows highly sensitive, high-resolution detection of the evanescent field alone and promises new capabilities for high-resolution terahertz imaging.
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Финкель, М. И. (2006). Терагерцовые смесители на эффекте электронного разогрева в ультратонких плёнках NbN и NbTiN. Ph.D. thesis, , .
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Rath, P., Vetter, A., Kovalyuk, V., Ferrari, S., Kahl, O., Nebel, C., et al. (2016). Travelling-wave single-photon detectors integrated with diamond photonic circuits: operation at visible and telecom wavelengths with a timing jitter down to 23 ps. In J. - E. Broquin, & G. N. Conti (Eds.), Integrated Optics: Devices, Mat. Technol. XX (Vol. 9750, pp. 135–142). Spie.
Abstract: We report on the design, fabrication and measurement of travelling-wave superconducting nanowire single-photon detectors (SNSPDs) integrated with polycrystalline diamond photonic circuits. We analyze their performance both in the near-infrared wavelength regime around 1600 nm and at 765 nm. Near-IR detection is important for compatibility with the telecommunication infrastructure, while operation in the visible wavelength range is relevant for compatibility with the emission line of silicon vacancy centers in diamond which can be used as efficient single-photon sources. Our detectors feature high critical currents (up to 31 μA) and high performance in terms of efficiency (up to 74% at 765 nm), noise-equivalent power (down to 4.4×10-19 W/Hz1/2 at 765 nm) and timing jitter (down to 23 ps).
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Doerr, C. R., Zhang, C., & Winzer, P. J. (2010). Monolithic InP multi-wavelength coherent receiver. In Conference on optical fiber communication, collocated national fiber optic engineers conference (pp. 1–3).
Abstract: We propose and demonstrate a novel four-channel monolithic polarization-diversity dual-quadrature coherent receiver with balanced detection in InP. It uses an interleave-chirped arrayed waveguide grating that acts simultaneously as a demultiplexer, 90° hybrid, and polarization splitter.
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Il'in, K. S., Lindgren, M., Currie, M. A., Semenov, D., Gol'tsman, G. N., Sobolewski, R., et al. (2000). Picosecond hot-electron energy relaxation in NbN superconducting photodetectors. Appl. Phys. Lett., 76(19), 2752–2754.
Abstract: We report time-resolved characterization of superconducting NbN hot-electron photodetectors using an electro-optic sampling method. Our samples were patterned into micron-size microbridges from 3.5-nm-thick NbN films deposited on sapphire substrates. The devices were illuminated with 100 fs optical pulses, and the photoresponse was measured in the ambient temperature range between 2.15 and 10.6 K (superconducting temperature transition TC). The experimental data agreed very well with the nonequilibrium hot-electron, two-temperature model. The quasiparticle thermalization time was ambient temperature independent and was measured to be 6.5 ps. The inelastic electron–phonon scattering time Ï„e–ph tended to decrease with the temperature increase, although its change remained within the experimental error, while the phonon escape time Ï„es decreased almost by a factor of two when the sample was put in direct contact with superfluid helium. Specifically, Ï„e–ph and Ï„es, fitted by the two-temperature model, were equal to 11.6 and 21 ps at 2.15 K, and 10(±2) and 38 ps at 10.5 K, respectively. The obtained value of Ï„e–ph shows that the maximum intermediate frequency bandwidth of NbN hot-electron phonon-cooled mixers operating at TC can reach 16(+4/–3) GHz if one eliminates the bolometric phonon-heating effect.
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Cherednichenko, S., Drakinskiy, V., Berg, T., Khosropanah, P., & Kollberg, E. (2008). Hot-electron bolometer terahertz mixers for the Herschel Space Observatory. Rev. Sci. Instrum., 79, 034501.
Abstract: We report on low noise terahertz mixers(1.4–1.9THz) developed for the heterodyne spectrometer onboard the Herschel Space Observatory. The mixers employ double slot antenna integrated superconducting hot-electron bolometers (HEBs) made of thin NbN films. The mixer performance was characterized in terms of detection sensitivity across the entire rf band by using a Fourier transform spectrometer (from 0.5to2.5THz, with 30GHz resolution) and also by measuring the mixernoise temperature at a limited number of discrete frequencies. The lowest mixernoise temperature recorded was 750K [double sideband (DSB)] at 1.6THz and 950KDSB at 1.9THz local oscillator (LO) frequencies. Averaged across the intermediate frequency band of 2.4–4.8GHz, the mixernoise temperature was 1100KDSB at 1.6THz and 1450KDSB at 1.9THz LO frequencies. The HEB heterodyne receiver stability has been analyzed and compared to the HEB stability in the direct detection mode. The optimal local oscillator power was determined and found to be in a 200–500nW range.
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