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Author (up) Dickert, F. L.; Haunschild, A.; Kuschow, V.; Reif, M.; Stathopulos, H. url  doi
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  Title Mass-sensitive detection of solvent vapors. Mechanistic studies on host-guest sensor principles by FT-IR spectroscopy and BET adsorption analysis Type Journal Article
  Year 1996 Publication Analytical Chemistry Abbreviated Journal Anal. Chem.  
  Volume 68 Issue 6 Pages 1058-1061  
  Keywords supramolecular recognition, quartz crystal microbalance, QCM, surface acoustic wave, SAW, mass-sensitive sensor, detector, calixarenes, MM3 force field, Brunauer, Emmett and Teller theory, BET  
  Abstract Chemical sensors, based on highly mass sensitive QMB or SAW devices, coated with thin layers of calixarenes, enable the detection of organic solvent vapours, especially halogenated or aromatic hydrocarbons, down to a few ppm. Force field calculations allow the tailoring of these sensor materials seeing that the predicted interaction energies between the host molecules and a large variety of analytes are linearly correlated to the measured sensor effects. These correlations and also BET adsorption analysis prove the analyte recognition properties of these calixarene coatings to be mainly based on host/guest inclusion principles.  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number Serial 562  
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