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Author |
Dickert, Franz L. |
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Title |
Christoph A. Schalley (Ed.): Analytical methods in supramolecular chemistry |
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Journal Article |
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Year |
2007 |
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Analytical and Bioanalytical Chemistry |
Abbreviated Journal |
Anal Bioanal Chem |
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Volume |
389 |
Issue |
7-8 |
Pages |
2039-2040 |
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Keywords |
supramolecular recognition |
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This is a review of book. |
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1618-2642 |
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563 |
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Lieberzeit, Peter A.; Dickert, Franz L. |
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Title |
Chemosensors in environmental monitoring: challenges in ruggedness and selectivity |
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Journal Article |
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Year |
2009 |
Publication |
Analytical and Bioanalytical Chemistry |
Abbreviated Journal |
Anal Bioanal Chem |
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Volume |
393 |
Issue |
2 |
Pages |
467-472 |
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Keywords |
environmental monitoring, in situ sensing, artificial recognition materials, real-life application, molecular imprinting, QCM |
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Abstract |
Environmental analysis is a potential key application for chemical sensors owing to their inherent ability to detect analytes on-line and in real time in distributed systems. Operating a chemosensor in a natural environment poses substantial challenges in terms of ruggedness, long-term stability and calibration. This article highlights current trends of achieving both the necessary selectivity and ruggedness: one way is deploying sensor arrays consisting of robust broadband sensors and extracting information via chemometrics. If using only a single sensor is desired, molecularly imprinted polymers offer a straightforward way for designing artificial recognition materials. Molecularly imprinted polymers can be utilized in real-life environments, such as water and air, aiming at detecting analytes ranging from small molecules to entire cells. |
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1618-2642 |
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564 |
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Dickert, F. L.; Haunschild, A.; Kuschow, V.; Reif, M.; Stathopulos, H. |
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Title |
Mass-sensitive detection of solvent vapors. Mechanistic studies on host-guest sensor principles by FT-IR spectroscopy and BET adsorption analysis |
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Journal Article |
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1996 |
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Analytical Chemistry |
Abbreviated Journal |
Anal. Chem. |
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68 |
Issue |
6 |
Pages |
1058-1061 |
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Keywords |
supramolecular recognition, quartz crystal microbalance, QCM, surface acoustic wave, SAW, mass-sensitive sensor, detector, calixarenes, MM3 force field, Brunauer, Emmett and Teller theory, BET |
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Chemical sensors, based on highly mass sensitive QMB or SAW devices, coated with thin layers of calixarenes, enable the detection of organic solvent vapours, especially halogenated or aromatic hydrocarbons, down to a few ppm. Force field calculations allow the tailoring of these sensor materials seeing that the predicted interaction energies between the host molecules and a large variety of analytes are linearly correlated to the measured sensor effects. These correlations and also BET adsorption analysis prove the analyte recognition properties of these calixarene coatings to be mainly based on host/guest inclusion principles. |
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0003-2700 |
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562 |
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Soifer, B. T.; Pipher, J. L. |
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Instrumentation for infrared astronomy |
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1978 |
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Annual Rev. Astron. Astrophys. |
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16 |
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1 |
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335-369 |
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infrared applications |
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0066-4146 |
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492 |
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Crockett, N. R.; Bergin, E. A.; Wang, S.; Lis, D. C.; Bell, T. A.; Blake, G. A.; Boogert, A.; Bumble, B.; Cabrit, S.; Caux, E.; Ceccarelli, C.; Cernicharo, J.; Comito, C.; Daniel, F.; Dubernet, M.-L.; Emprechtinger, M.; Encrenaz, P.; Falgarone, E.; Gerin, M.; Giesen, T. F.; Goicoechea, J. R.; Goldsmith, P. F.; Gupta, H.; Güsten, R.; Hartogh, P.; Helmich, F.; Herbst, E.; Honingh, N.; Joblin, C.; Johnstone, D.; Karpov, A.; Kawamura, J. H.; Kooi, J.; Krieg, J.-M.; Langer, W. D.; Latter, W. D.; Lord, S. D.; Maret, S.; Martin, P. G.; Melnick, G. J.; Menten, K. M.; Morris, P.; Müller, H. S. P.; Murphy, J. A.; Neufeld, D. A.; Ossenkopf, V.; Pearson, J. C.; Pérault, M.; Phillips, T. G.; Plume, R.; Qin, S.-L.; Roelfsema, P.; Schieder, R.; Schilke, P.; Schlemmer, S.; Stutzki, J.; van der Tak, F. F. S.; Tielens, A.; Trappe, N.; Vastel, C.; Yorke, H. W.; Yu, S.; Zmuidzinas, J. |
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Title |
Herschel observations of EXtra-Ordinary Sources (HEXOS): The Terahertz spectrum of Orion KL seen at high spectral resolution |
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Journal Article |
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Year |
2010 |
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Annual Rev. Astron. Astrophys. |
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521 |
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L21 (1 to 5) |
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HEB mixer applications, HIFI, Herschel |
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We present the first high spectral resolution observations of Orion KL in the frequency ranges 1573.4–1702.8 GHz (band 6b) and 1788.4–1906.8 GHz (band 7b) obtained using the HIFI instrument on board the Herschel Space Observatory. We characterize the main emission lines found in the spectrum, which primarily arise from a range of components associated with Orion KL including the hot core, but also see widespread emission from components associated with molecular outflows traced by H2O, SO2, and OH. We find that the density of observed emission lines is significantly diminished in these bands compared to lower frequency Herschel/HIFI bands. |
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1087 |
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