Abstract: A new multifrequency quasioptical electron paramagnetic resonance (EPR) spectrometer is described. The superheterodyne design with Schottky diode mixer/detectors enables fast detection with subnanosecond time resolution. Optical access makes it suitable for transient EPR (TR-EPR) at 120 and 240 GHz. These high frequencies allow for an accurate determination of small g-tensor anisotropies as are encountered in excited triplet states of organic molecules like porphyrins and fullerenes. The measured concentration sensitivity for continuous-wave (cw) EPR at 240 GHz and at room temperature without cavity is 1013 spins/cm3 (15 nM) for a 1 mT linewidth and a 1 Hz bandwidth. With a Fabry-Perot cavity and a sample volume of 30 nl, the sensitivity at 240 GHz corresponds to [approximate]3×109 spins for a 1 mT linewidth. The spectrometer's performance is illustrated with applications of transient EPR of excited triplet states of organic molecules, as well as cw EPR of nitroxide reference systems and a thin film of a colossal magnetoresistance material.

Abstract: Antenna-coupled optical detectors, also named optical antennas, are being developed and proposed as alternative detection devices for the millimetre, infrared, and visible spectra. Optical and infrared antennas represent a class of optical components that couple electromagnetic radiation in the visible and infrared wavelengths in the same way as radioelectric antennas do at the corresponding wavelengths. The size of optical antennas is in the range of the detected wavelength and they involve fabrication techniques with nanoscale spatial resolution. Optical antennas have already proved and potential advantages in the detection of light showing polarization dependence, tuneability, and rapid time response. They also can be considered as point detectors and directionally sensitive elements. So far, these detectors have been thoroughly tested in the mid-infrared with some positive results in the visible. The measurement and characterization of optical antennas requires the use of an experimental set-up with nanometric resolution. On the other hand, a computation simulation of the interaction between the material structures and the incoming electromagnetic radiation is needed to explore alternative designs of practical devices.

Abstract: Hot-electron bolometer devices, used successfully in low noise heterodyne mixing at frequencies up to 2.5 THz, have been analyzed. A distributed temperature numerical model of the NbN bridge, based on a local electron and a phonon temperature, is used to model pumped IV curves and understand the physical conditions during the mixing process. We argue that the mixing is predominantly due to the strongly temperature dependent local resistivity of the NbN. Experimentally we identify the origins of different transition temperatures in a real HEB device, suggesting the importance of the intrinsic resistive transition of the superconducting bridge in the modeling.